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阀上实验室系统中90Sr的自动化分离与预富集,达到皮克每升水平。

Automated 90Sr Separation and Preconcentration in a Lab-on-Valve System at Ppq Level.

作者信息

Vicente Vilas Victor, Millet Sylvain, Sandow Miguel, Aldave de Las Heras Laura

机构信息

Directorate G - Nuclear Safety & Security, Unit G.III. 8 - Waste Management, European Commission, DG Joint Research Centre - JRC.

Directorate G - Nuclear Safety & Security, Unit G.III. 8 - Waste Management, European Commission, DG Joint Research Centre - JRC;

出版信息

J Vis Exp. 2018 Jun 6(136):57722. doi: 10.3791/57722.

DOI:10.3791/57722
PMID:29939189
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6101560/
Abstract

A quick, automated and portable system for the separation and determination of radiostrontium in aqueous samples, using Sr-resin and multi sequential flow injection analysis, has been developed. The concentrations of radioactive strontium were determined by flow scintillation counting, allowing for on-line and also on-site determination. The proposed system can determine radioactive strontium at industrial relevant levels without further modification using overall analysis time of less than 10 min per aqueous sample. The limit of the detection is 320 fg·g (1.7 Bq/g).

摘要

已经开发出一种快速、自动化且便携的系统,该系统使用锶树脂和多序贯流动注射分析来分离和测定水样中的放射性锶。通过流动闪烁计数法测定放射性锶的浓度,可实现在线和现场测定。所提出的系统无需进一步修改,即可在工业相关水平下测定放射性锶,每个水样的总分析时间不到10分钟。检测限为320 fg·g(1.7 Bq/g)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6101560/b45532b6455b/jove-136-57722-4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6101560/64ad4de9835a/jove-136-57722-0.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6101560/8634cf1abede/jove-136-57722-1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6101560/e7edba596b3b/jove-136-57722-2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6101560/b8b04043d500/jove-136-57722-3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6101560/b45532b6455b/jove-136-57722-4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6101560/64ad4de9835a/jove-136-57722-0.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6101560/8634cf1abede/jove-136-57722-1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6101560/e7edba596b3b/jove-136-57722-2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6101560/b8b04043d500/jove-136-57722-3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1291/6101560/b45532b6455b/jove-136-57722-4.jpg

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本文引用的文献

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A LabVIEW-based software for the control of the AUTORAD platform: a fully automated multisequential flow injection analysis Lab-on-Valve (MSFIA-LOV) system for radiochemical analysis.一种基于LabVIEW的用于控制AUTORAD平台的软件:一种用于放射化学分析的全自动多序列流动注射分析阀上实验室(MSFIA-LOV)系统。
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Automation of sample processing for ICP-MS determination of Sr radionuclide at ppq level for nuclear technology and environmental purposes.用于核技术和环境目的的电感耦合等离子体质谱法(ICP-MS)测定痕量锶放射性核素的样品处理自动化。
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Development of radiochemical analysis strategies for decommissioning activities.
退役活动放射化学分析策略的制定。
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Time optimization of (90)Sr measurements: Sequential measurement of multiple samples during ingrowth of (90)Y.(90)锶测量的时间优化:在(90)钇生长期间对多个样品进行顺序测量。
Appl Radiat Isot. 2016 Apr;110:150-154. doi: 10.1016/j.apradiso.2016.01.011. Epub 2016 Jan 8.
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Determination of low-level radiostrontium, with emphasis on in situ pre-concentration of Sr from large volume of freshwater sample using Powdex resin.低水平放射性锶的测定,重点是使用粉末树脂从大量淡水样品中原位预富集锶。
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Automation of ⁹⁹Tc extraction by LOV prior ICP-MS detection: application to environmental samples.电感耦合等离子体质谱检测前通过光化学衍生装置进行⁹⁹Tc萃取的自动化:应用于环境样品。
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Determination of ⁹⁰Sr and ²¹⁰Pb in sludge samples using a LOV-MSFIA system and liquid scintillation counting.使用低压有机挥发物微流控免疫分析系统和液体闪烁计数法测定污泥样品中的⁹⁰Sr和²¹⁰Pb。
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Automatic and simple method for ⁹⁹Tc determination using a selective resin and liquid scintillation detection applied to urine samples.采用选择性树脂和液体闪烁探测的 ⁹⁹Tc 自动简单测定法及其在尿样中的应用。
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Automated total and radioactive strontium separation and preconcentration in samples of environmental interest exploiting a lab-on-valve system.利用阀上实验室系统自动进行环境感兴趣样品中的总锶和放射性锶分离与预浓缩。
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Evaluation of flow scintillation analysis for the determination of Sr-90 in bioassay samples.用于生物测定样品中锶-90测定的流动闪烁分析评估
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