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微波辅助消解法-四极杆电感耦合等离子体质谱法测定海藻中的矿物和微量元素浓度。

Mineral and Trace Metal Concentrations in Seaweeds by Microwave-Assisted Digestion Method Followed by Quadrupole Inductively Coupled Plasma Mass Spectrometry.

机构信息

Ecotoxicology Division, Centre for Ocean Research, Col. Dr. Jeppiar Research Park, Sathyabama Institute of Science and Technology, Chennai, India.

出版信息

Biol Trace Elem Res. 2019 Feb;187(2):579-585. doi: 10.1007/s12011-018-1397-8. Epub 2018 Jun 11.

Abstract

This study reports the total concentrations of mineral and trace metals sodium, potassium, calcium, magnesium, phosphorus, iron, copper, zinc, and manganese in the seaweeds Padina tetrastromatica, Turbinaria ornate, Sargassum wightii, Sargassum swartzii, Gracilaria edulis, Ulva lactuca, Chaetomorpha antennina, and Halimeda opuntia collected from mandapam coastal regions, Southeast coast of India. Microwave-assisted digestion was used for sample preparation prior to mineral and trace metal analysis. Mineral and trace metal analyses were determined by inductively coupled plasma mass spectrometry. The ranges of concentrations of mineral and trace metals in algae were 27.04 ± 2.54-194.08 ± 2.36 mg/kg for manganese, 1.88 ± 0.10-121.5 ± 0.70 mg/kg for sodium, 6.5 ± 0.56-90.5 ± 2.12 mg/kg for magnesium, 59.07 ± 0.34-672 ± 2.82 mg/kg for potassium, 13.15 ± 2.08-135.13 ± 1.59 for sulfur, 0.003 ± 0.001-3.44 ± 0.13 mg/kg for cobalt, 0.39 ± 0.19-8.95 ± 0.38 mg/kg for copper, 0.72 ± 0.28-25.72 ± 0.39 mg/kg for zinc, and 6.01 ± 0.27-188.47 ± 1.92 mg/kg for iron.The results were evaluated statistically, and the significant difference was observed in the mean concentrations of all mineral and trace elements, except Co, Cu, and Zn, among the type of seaweeds.

摘要

本研究报告了从印度东南海岸曼达潘沿海地区采集的海藻 Padina tetrastromatica、Turbinaria ornate、Sargassum wightii、Sargassum swartzii、Gracilaria edulis、Ulva lactuca、Chaetomorpha antennina 和 Halimeda opuntia 中钠、钾、钙、镁、磷、铁、铜、锌和锰等矿物质和微量元素的总浓度。在进行矿物质和微量元素分析之前,使用微波辅助消化法对样品进行了制备。通过电感耦合等离子体质谱法测定了矿物质和微量元素的浓度。藻类中矿物质和微量元素的浓度范围为:锰 27.04±2.54-194.08±2.36mg/kg,钠 1.88±0.10-121.5±0.70mg/kg,镁 6.5±0.56-90.5±2.12mg/kg,钾 59.07±0.34-672±2.82mg/kg,硫 13.15±2.08-135.13±1.59mg/kg,钴 0.003±0.001-3.44±0.13mg/kg,铜 0.39±0.19-8.95±0.38mg/kg,锌 0.72±0.28-25.72±0.39mg/kg,铁 6.01±0.27-188.47±1.92mg/kg。对结果进行了统计评估,除钴、铜和锌外,所有矿物质和微量元素的平均浓度在不同海藻类型之间存在显著差异。

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