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铷铁氢砷酸盐(RbFe(HAsO))和铊铁氢砷酸盐(TlFe(HAsO)),两种采用两种紧密相关结构类型的新型氢砷酸盐。

RbFe(HAsO) and TlFe(HAsO), two new hydrogenarsenates adopting two closely related structure types.

作者信息

Schwendtner Karolina, Kolitsch Uwe

机构信息

Institute for Chemical Technology and Analytics, Division of Structural Chemistry, TU Wien, Getreidemarkt 9/164-SC, 1060 Vienna, Austria.

Naturhistorisches Museum, Burgring 7, 1010 Wien, and Institut für Mineralogie und Kristallographie, Universität Wien, Althanstrasse 14, 1090 Wien, Austria.

出版信息

Acta Crystallogr E Crystallogr Commun. 2018 May 1;74(Pt 6):766-771. doi: 10.1107/S2056989018006473. eCollection 2018 Jun 1.

DOI:10.1107/S2056989018006473
PMID:29951226
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6002822/
Abstract

Rubidium iron bis-[hydrogen arsenate(V)], RbFe(HAsO), and thallium iron bis-[hydrogen arsenate(V)], TlFe(HAsO), were grown under mild hydro-thermal conditions ( = 493 K, 7 d). RbFe(HAsO) adopts the RbFe(HPO) structure type (space group ), while TlFe(HAsO) crystallizes in the (NH)Fe(HPO) structure type (space group ). Both compounds have tetra-hedral-octa-hedral framework topologies. The cations are located in channels of the respective framework and are disordered in TlFe(HAsO), which may suggest that the cations can move in the channels.

摘要

铷铁双[砷酸氢(V)],RbFe(HAsO₄),和铊铁双[砷酸氢(V)],TlFe(HAsO₄),在温和水热条件下(493 K,7天)生长。RbFe(HAsO₄)采用RbFe(HPO₄)结构类型(空间群),而TlFe(HAsO₄)以(NH₄)Fe(HPO₄)结构类型结晶(空间群)。两种化合物都具有四面体-八面体框架拓扑结构。阳离子位于各自框架的通道中,并且在TlFe(HAsO₄)中无序,这可能表明阳离子可以在通道中移动。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45cc/6002822/f7514091a147/e-74-00766-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45cc/6002822/05da810c2f2a/e-74-00766-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45cc/6002822/b0fd61ac12ad/e-74-00766-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45cc/6002822/c67a3d3a42e1/e-74-00766-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45cc/6002822/f7514091a147/e-74-00766-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45cc/6002822/05da810c2f2a/e-74-00766-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45cc/6002822/b0fd61ac12ad/e-74-00766-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45cc/6002822/c67a3d3a42e1/e-74-00766-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45cc/6002822/f7514091a147/e-74-00766-fig4.jpg

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本文引用的文献

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