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金属有机骨架材料在常见芳香族污染物吸附中的最新进展。

Recent advances in metal-organic frameworks for adsorption of common aromatic pollutants.

机构信息

College of Chemistry and Environmental Sience, Key Laboratory of Analytical Science and Technology of Hebei Province, Hebei University, Baoding, 071002, China.

出版信息

Mikrochim Acta. 2018 Jun 27;185(7):342. doi: 10.1007/s00604-018-2879-2.

Abstract

This review (with 85 refs.) summarizes the recent literature on the adsorption of common aromatic pollutants by using modified metal-organic frameworks (MOFs). Four kinds of aromatic pollutants are discussed, namely benzene homologues, polycyclic aromatic hydrocarbons (PAHs), organic dyes and their intermediates, and pharmaceuticals and personal care products (PPCPs). MOFs are shown to be excellent adsorbents that can be employed to both the elimination of pollutants and to their extraction and quantitation. Adsorption mechanisms and interactions between aromatic pollutants and MOFs are discussed. Finally, the actual challenges of existence and the perspective routes towards future improvements in the field are addressed. Graphical abstract Recent advance on adsorption of common aromatic pollutants including benzene series, polycyclic aromatic hydrocarbons, organic dyes and their intermediates, pharmaceuticals and personal care products by metal-organic frameworks.

摘要

这篇综述(引用了 85 篇参考文献)总结了近年来使用改性金属-有机框架(MOFs)吸附常见芳香族污染物的文献。讨论了四种芳香族污染物,即苯同系物、多环芳烃(PAHs)、有机染料及其中间体以及药品和个人护理用品(PPCPs)。结果表明,MOFs 是一种优良的吸附剂,可用于消除污染物以及提取和定量分析污染物。讨论了芳香族污染物与 MOFs 之间的吸附机制和相互作用。最后,讨论了该领域存在的实际挑战和未来改进的途径。

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