膦催化的 Morita-Baylis-Hillman 碳酸酯的对映选择性[4+2]环加成-半频哪醇型重排反应。
Phosphine-Catalyzed Enantioselective [4 + 2] Cycloaddition-Semipinacol-Type-Rearrangement Reaction of Morita-Baylis-Hillman Carbonates.
机构信息
School of Pharmaceutical Sciences , Sun Yat-Sen University , Guangzhou , 510006 , China.
Key Laboratory of Preclinical Study for New Drugs of Gansu Province, School of Basic Medical Sciences , Lanzhou University , Lanzhou , 730000 , China.
出版信息
Org Lett. 2018 Jul 20;20(14):4250-4254. doi: 10.1021/acs.orglett.8b01661. Epub 2018 Jun 28.
PMID:29952572
Abstract
The chiral phosphine-triggered electrophilic ylide intermediate for a Morita-Baylis-Hillman carbonates activation strategy provides a promising method for the design of organocatalytic intermolecular higher-order annulation processes.
摘要
手性膦触发的亲电叶立德中间体用于 Morita-Baylis-Hillman 碳酸酯激活策略，为设计有机催化的分子间高阶环化反应提供了一种很有前途的方法。
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