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用于热电应用的纳米结构碲化物及其异质结构——综述

Nanostructured Metal Tellurides and Their Heterostructures for Thermoelectric Applications-A Review.

作者信息

Karunanithy M, Prabhavathi G, Beevi A Hameedha, Ibraheem B H Ahmed, Kaviyarasu K, Nivetha S, Punithavelan N, Ayeshamariam A, Jayachandran M

出版信息

J Nanosci Nanotechnol. 2018 Oct 1;18(10):6680-6707. doi: 10.1166/jnn.2018.15731.

Abstract

Telluride's and Selenides were assessed whether it is appropriate for thermoelectric effects. Previous researches showed that researchers strived to progress the performance of telluride based materials in creating structures where the entire dimensions are reduced, such as nanowires or thin films. Seebeck and Peltier coefficient was developed by means of Telluride thermoelectric devices. Epitaxial growth methods such as molecular beam epitaxy and metal organic chemical vapor deposition are some of the frequent methods of acquiring telluride thin films. Thermoelectric nano thin films and nanostructured materials should have the properties of insulation so that it can be used as energy storage devices and thermo electric generators. Conduction of electricity is usually convoyed by reversible and irreversible effects, such as electrical resistance and thermal conduction which is used to, Peltier refrigerators, generating electricity, renewable energies and its applications. Telluride films can be used in thermoelectric applications; these thermoelectric materials are mainly rare metals such as (Bi), (Te), (Pb) and (Sb). Thermal conductivity, figure of merit is advantageous factor of these energy storage devices. Thermoelectric cooler, thermoelectric generators are the powerful sources which can be eligible due to the use of telluride thin films. The thermal conductivity performance, figure of merit and Seebeck and Peltier coefficients of diverse materials were conferred.

摘要

对碲化物和硒化物是否适用于热电效应进行了评估。先前的研究表明,研究人员致力于在制造诸如纳米线或薄膜等全尺寸减小的结构中提高碲基材料的性能。碲化物热电器件得出了塞贝克系数和帕尔贴系数。诸如分子束外延和金属有机化学气相沉积等外延生长方法是获取碲化物薄膜的一些常见方法。热电纳米薄膜和纳米结构材料应具有绝缘特性,以便用作能量存储装置和热电发电机。导电通常由可逆和不可逆效应传递,例如用于珀耳帖制冷器、发电、可再生能源及其应用的电阻和热传导。碲化物薄膜可用于热电应用;这些热电材料主要是稀有金属,如铋(Bi)、碲(Te)、铅(Pb)和锑(Sb)。热导率、品质因数是这些能量存储装置的有利因素。热电冷却器、热电发电机是由于使用碲化物薄膜而可能符合条件的强大能源。文中给出了不同材料的热导率性能、品质因数以及塞贝克系数和帕尔贴系数。

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