Synthesis and Characterization of Benzodithiophene-4,8-Dione-Based Copolymers for Polymer Solar Cells.

A novel series of benzodithiophene-4,8-dione (BDD)-based copolymers, poly[(4,4,9,9-tetrakis(4-hexylphenyl)-4,9-dihydro-s-indacenodithiophene-2,7-diyl)-alt-(1,3-bis(2-ethylhexyl)-5,7-di(thiophene2-yl)benzodithiophene-4,8-dione)] (P1) and poly[(5,5,11,11-tetrakis(4-hexylphenyl)dithieno[2,3-d: 2',3'-d']-s-indacenodithiophene-3,9-diyl)-alt-(1,3-bis(2-ethylhexyl)-5,7-di(thiophene-2-yl)benzodithiophene-4,8-dione)] (P2), which have the same acceptor moiety but different donor segments, have been designed and synthesized for use as donor materials in solution-processable polymer solar cells (PSCs). The optical and photovoltaic properties of the copolymers were investigated. The band gaps of the copolymers were in the range 1.91-1.92 eV. Under optimized conditions, the BDD-based polymers showed power conversion efficiencies (PCEs) for the PSCs in the range 2.52-2.92% under AM 1.5 illumination (100 mW/cm2). Among the copolymers, P1, which contained an indacenodithiophene donor unit, showed a power conversion efficiency of 2.92% with a short circuit current of 7.30 mA/cm2, open circuit voltage of 0.92 V, and a fill factor of 0.43, under AM 1.5 illumination (100 mW/cm2).