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[中国台湾海峡西岸沿海城市群PM中重金属污染特征及其对人体健康的风险]

[Pollution Characteristics of Heavy Metals in PM and Their Human Health Risks Among the Coastal City Group Along Western Taiwan Straits Region, China].

作者信息

Chen Yan-Ting, Du Wen-Jiao, Chen Jin-Sheng, Xu Ling-Ling

机构信息

Center for Excellence in Urban Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China.

Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China.

出版信息

Huan Jing Ke Xue. 2017 Feb 8;38(2):429-437. doi: 10.13227/j.hjkx.201606077.

Abstract

PM samples were collected from 11 sampling sites in the coastal city group along western Taiwan Straits region, China, and these heavy metal elements (Zn, Cu, Pb, Ni, Cr, As) were detected using particle-induced X-ray emission (PIXE) method. The pollution characteristics, enrichment factors and source apportionment of heavy metals in PM were analyzed, and furthermore, their human health risks were determined. The result showed concentration distribution was obviously different between PM and heavy metals in the city group, for the main sources (e.g. construction dust and ground dust) for PM were not the main contribution to these heavy metals. The enrichment factors of Zn, Cu, Pb, Mn, Ni, Cr, As exceeded 10, which suggested these metals were enriched and significantly impacted by anthropogenic pollution. Three main groups of heavy metals in PM were identified by principal component analysis (PCA-MLR), such as coal combustion and traffic emissions (70.59%), multiple sources (coal and oil combustion, pyrometallurgical process, 17.55%) and other industry (11.86%). The risk levels for carcinogenic heavy metals (Ni, Cr, As) and non-carcinogenic heavy metals (Zn, Cu, Pb, Mn) were lower than the average level of risk acceptance (10), which suggested these heavy metals did not cause harm to human health in these cities.

摘要

在中国台湾海峡西岸沿海城市群的11个采样点采集了可吸入颗粒物(PM)样本,并使用粒子诱导X射线发射(PIXE)方法检测了这些重金属元素(锌、铜、铅、镍、铬、砷)。分析了可吸入颗粒物中重金属的污染特征、富集因子和来源分配,此外,还确定了它们对人体健康的风险。结果表明,城市群中可吸入颗粒物和重金属的浓度分布明显不同,因为可吸入颗粒物的主要来源(如建筑扬尘和地面灰尘)对这些重金属的贡献不大。锌、铜、铅、锰、镍、铬、砷的富集因子超过10,这表明这些金属已富集且受到人为污染的显著影响。通过主成分分析(PCA-MLR)确定了可吸入颗粒物中重金属的三个主要类别,如煤炭燃烧和交通排放(70.59%)、多种来源(煤炭和石油燃烧、火法冶金过程,17.55%)以及其他行业(11.86%)。致癌重金属(镍、铬、砷)和非致癌重金属(锌、铜、铅、锰)的风险水平低于风险接受平均水平(10),这表明这些重金属在这些城市中不会对人体健康造成危害。

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