Guo Yan-Hai, Sun Xu-Chao, Zhang Shi-Bing, Yu Guang-Jie, Tang Zheng, Liu Zhen-Hong, Xue Gang, Gao Pin
State Environmental Protection Engineering Center for Pollution Treatment and Control in Textile Industry, College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China.
Huan Jing Ke Xue. 2017 Dec 8;38(12):5262-5271. doi: 10.13227/j.hjkx.201704113.
The contents of ten heavy metals (As, Cu, Cd, Cr, Pb, Ni, Zn, Ti, Mn, and Hg) were determined in the surface soils surrounding a municipal solid waste incineration plant in Shanghai using atomic spectroscopy. The spatial distribution and sources of the detected heavy metals were studied by enrichment factor and multivariate statistical and spatial interpolation analyses. In addition, their potential ecological risk was assessed. The results showed that all heavy metals, except Hg and As, were detected with mean contents ranging from 0.399 to 4220 mg·kg. The mean contents of Cu, Cd, Cr, Pb, Ni, Zn, and Mn were higher than their respective background values in Shanghai. In particular, the mean content of Cd was 2.9 times its background value. The results of the Pearson's correlation, principle component, enrichment factor, and spatial distribution analyses of these heavy metals indicated that Ti, Mn, and Ni primarily originated from natural sources, while Cd, Cr, Cu, Pb, and Zn originated from industrial manufacturing, combustion, and traffic emissions. The potential ecological risk assessment showed that soils surrounding the municipal solid waste incineration plant suffered from a moderate-level risk. The mean value of the potential ecological risk index of these detected heavy metals was 108.92, of which Cd contributed as high as 79.63%, deserving much attention.
采用原子光谱法测定了上海某城市生活垃圾焚烧厂周边表层土壤中10种重金属(砷、铜、镉、铬、铅、镍、锌、钛、锰和汞)的含量。通过富集因子、多元统计和空间插值分析研究了所检测重金属的空间分布和来源。此外,还评估了它们的潜在生态风险。结果表明,除汞和砷外,所有重金属均被检测到,平均含量范围为0.399至4220 mg·kg。铜、镉、铬、铅、镍、锌和锰的平均含量高于上海各自的背景值。特别是,镉的平均含量是其背景值的2.9倍。这些重金属的Pearson相关性、主成分、富集因子和空间分布分析结果表明,钛、锰和镍主要来源于自然源,而镉、铬、铜、铅和锌则来源于工业制造、燃烧和交通排放。潜在生态风险评估表明,城市生活垃圾焚烧厂周边土壤存在中等程度的风险。所检测重金属的潜在生态风险指数平均值为108.92,其中镉的贡献率高达79.63%,值得高度关注。