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[巢湖溶解态重金属的时空分布及污染评价]

[Temporal-spatial Distribution and Pollution Assessment of Dissolved Heavy Metals in Chaohu Lake].

作者信息

Wu Lei, Liu Gui-Jian, Zhou Chun-Cai, Liu Rong-Qiong

机构信息

School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, China.

Anhui Academy of Environmental Science and Research, Hefei 230022, China.

出版信息

Huan Jing Ke Xue. 2018 Feb 8;39(2):738-747. doi: 10.13227/j.hjkx.201703099.

Abstract

Surface water samples were collected in different seasons from Chaohu Lake to determine the concentrations and potential environmental impacts of nine dissolved heavy metals (As, Hg, Cd, Cu, Pb, Zn, Cr, Ni, and Co). The concentrations of the selected heavy metals were determined by inductively coupled plasma-optical emission spectrometry (ICP-OES, ICAP6000 series). The single pollution index method and integrated pollution index method were used to evaluate the potential environmental impacts. The results indicated that the contents of dissolved As, Cd, Pb, and Cr in Chaohu Lake were lower than the limitations of GradeⅠof the Environmental Quality Standards for Surface Water (GB 3838-2002), while Cu and Zn were within the limitations of GradeⅠ-Ⅱ and Hg was within the limitations of GradeⅠ-Ⅲ. The contents of Ni and Co were far below the limitations. The concentrations of the selected heavy metals (Cu, Pb, Zn, Cr, Ni, and Co) varied among seasons and areas. Elevated concentrations of Cu, Zn, and Ni were found in summer, while elevated contents of Pb, Cr, and Co were found in autumn, autumn, and spring, respectively. Trace elements in the western part of Chaohu Lake (especially in the northwestern part) were higher than those in the middle and eastern parts for autumn, winter, and summer. Significant positive correlations were found among Cu, Pb, Zn, Cr, and Ni in the surface water, suggesting that these elements may derive from similar sources. The values of both the single factor pollution index and integrated pollution index of the selected elements in the surface water were far less than 1, suggesting that the environmental impacts could be regarded as negligible. The integrated pollution indices in the western part of the lake were higher than those of the middle and eastern parts on a one-year timescale, and the integrated pollution indices in each lake area followed a pattern of wet season (summer) > normal season (spring and autumn) > dry season (winter).

摘要

在不同季节采集巢湖的地表水样本,以测定9种溶解态重金属(砷、汞、镉、铜、铅、锌、铬、镍和钴)的浓度及其潜在环境影响。采用电感耦合等离子体发射光谱法(ICP-OES,ICAP6000系列)测定所选重金属的浓度。运用单因子污染指数法和综合污染指数法评估潜在环境影响。结果表明,巢湖溶解态砷、镉、铅和铬的含量低于《地表水环境质量标准》(GB 3838-2002)Ⅰ类标准限值,铜和锌在Ⅰ-Ⅱ类标准限值内,汞在Ⅰ-Ⅲ类标准限值内。镍和钴的含量远低于限值。所选重金属(铜、铅、锌、铬、镍和钴)的浓度随季节和区域而变化。夏季铜、锌和镍的浓度升高,而铅、铬和钴的含量分别在秋季、秋季和春季升高。巢湖西部(尤其是西北部)秋季、冬季和夏季的微量元素含量高于中部和东部。地表水中铜、铅、锌、铬和镍之间存在显著正相关,表明这些元素可能来自相似来源。地表水所选元素的单因子污染指数和综合污染指数值均远小于1,表明环境影响可忽略不计。在一年时间尺度上,湖泊西部的综合污染指数高于中部和东部,各湖区的综合污染指数呈现出雨季(夏季)>平季(春季和秋季)>旱季(冬季)的模式。

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