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[藻类形态和铝形态分布对混凝-超滤过程的影响]

[Effects of Algal Morphology and Al Species Distribution on the Coagulation-Ultrafiltration Process].

作者信息

Zhang Da-Wei, Xu Hui, Wang Xi, Men Bin, Wang Dong-Sheng, Duan Jin-Ming

机构信息

School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China.

State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.

出版信息

Huan Jing Ke Xue. 2017 Aug 8;38(8):3281-3289. doi: 10.13227/j.hjkx.201701130.

Abstract

In order to ensure drinking water quality, three different Al-based coagulants [Al(SO)(AS), Al, Al] were used to treat water laden with different algae [(cyanobacteria), (green algae), (diatoms)]. Floc size, strength factor, and recovery factor under different conditions were measured to investigate the mechanisms in the coagulation-ultrafiltration process. The results indicated that the main mechanism in the coagulation process using Al or Al as coagulants was electrostatic patching and the main mechanism using AS was charge neutralization. In the and systems, when Al and Al were used as coagulants at low dosage, the coagulants that were adsorbed on the side (which existed on the surfaces of and cells) would lose their ability to aggregate the algal cells. When AS was used as coagulant, the electric double layer was effectively compressed. The repulsive force between algal particles decreased, and the flocs formed easily. In the system, Al and Alcoagulants effectively formed the flocs through electrostatic patch effects. There was a significant correlation between membrane flux and floc size, and the larger flocs formed a looser cake layer on the membrane surface.

摘要

为确保饮用水质量,使用三种不同的铝基凝聚剂[硫酸铝(AS)、聚合氯化铝、聚合硫酸铝]处理含有不同藻类[蓝藻、绿藻、硅藻]的水。测量不同条件下的絮体尺寸、强度因子和回收率,以研究混凝-超滤过程中的机制。结果表明,以聚合氯化铝或聚合硫酸铝作为凝聚剂时,混凝过程的主要机制是静电补丁作用,而使用硫酸铝时的主要机制是电荷中和。在蓝藻和绿藻体系中,当低剂量使用聚合氯化铝和聚合硫酸铝作为凝聚剂时,吸附在蓝藻和绿藻细胞表面存在的负电荷一侧的凝聚剂会失去凝聚藻类细胞的能力。当使用硫酸铝作为凝聚剂时,有效压缩了双电层。藻类颗粒之间的排斥力降低,易于形成絮体。在硅藻体系中,聚合氯化铝和聚合硫酸铝凝聚剂通过静电补丁效应有效形成絮体。膜通量与絮体尺寸之间存在显著相关性,较大的絮体在膜表面形成较疏松的滤饼层。

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