Zhang Jia-Quan, Hu Tian-Peng, Xing Xin-Li, Zheng Huang, Zhang Li, Zhan Chang-Lin, Liu Hong-Xia, Xiao Wen-Sheng, Qi Shi-Hua
School of Environmental Science and Engineering, Hubei Polytechnic University, Huangshi 435003, China.
School of Environmental Studies, China University of Geosciences, Wuhan 430074, China.
Huan Jing Ke Xue. 2017 Jan 8;38(1):170-179. doi: 10.13227/j.hjkx.201606058.
8 surface sediments and 8 water samples were collected from the Daye Lake in August 2015.The 16 kinds of EPA control polycyclic aromatic hydrocarbons (PAHs) were analyzed by GC-MS.The results showed that the PAHs concentrations of surface sediments and water ranged from 35.94 ng·g to 2032.73 ng·g and from 27.94 ng·L to 242.95 ng·L,with average contents of 940.61 ng·g and 107.77ng·L,respectively.The distribution of PAHs in surface sediments indicated that the contents in the center samples were higher than those in the bank samples,but the water showed nearly the opposite tendency.The 4-5 rings high molecular weight PAHs were the main components in the surface sediments,and the 2,4 and 5 rings PAHs were given priority in water.Compared with the other domestic and oversea lakes,the PAHs pollution of the Daye Lake was at a moderate level.Source apportionment showed that the PAHs in surface sediments and water from the Daye Lake came from the combustion source,HWM-PAHs were the dominant part of the PAHs in the sediment,reflecting the sediment PAHs pollution under the effects of mining and smelting over a long period;All monomer PAHs and total PAHs content in sediment did not exceed the ERM and FEL limiting values,showing that there was no particularly serious ecological risk caused by PAHs in the surface sediments from the Daye Lake;the incremental lifetime cancer risks assessment showed that the uptake risk of PAHs in Daye Lake water through the ingestion and dermal absorption were both in the acceptable range recommended by the USEPA,but all sites had higher risk than the acceptable risk level recommended by the Sweden environmental protection agency and Royal society.The pollution of seven carcinogenic PAHs needs prevention and control.
2015年8月从大冶湖采集了8份表层沉积物和8份水样。采用气相色谱 - 质谱联用仪分析了16种美国环保署(EPA)管控的多环芳烃(PAHs)。结果表明,表层沉积物和水中PAHs浓度范围分别为35.94 ng·g至2032.73 ng·g和27.94 ng·L至242.95 ng·L,平均含量分别为940.61 ng·g和107.77 ng·L。PAHs在表层沉积物中的分布表明,湖心样品中的含量高于岸边样品,但水中情况几乎相反。4 - 5环的高分子量PAHs是表层沉积物中的主要成分,而2、4和5环PAHs在水中占主导。与其他国内外湖泊相比,大冶湖的PAHs污染处于中等水平。源解析表明,大冶湖表层沉积物和水中的PAHs来自燃烧源,HWM - PAHs是沉积物中PAHs的主要部分,反映了长期采矿和冶炼影响下沉积物PAHs污染情况;沉积物中所有单体PAHs和总PAHs含量均未超过ERM和FEL限值,表明大冶湖表层沉积物中PAHs未造成特别严重的生态风险;增量终生癌症风险评估表明,大冶湖水中PAHs通过摄入和皮肤吸收的摄取风险均在USEPA推荐的可接受范围内,但所有点位风险均高于瑞典环境保护局和皇家学会推荐的可接受风险水平。七种致癌PAHs的污染需要防控。