Li Chun-Fang, Wang Fei, Cao Wen-Tao, Pan Jian, Lü Jian-Shu, Wu Quan-Yuan
College of Geography and Environment, Shandong Normal University, Ji'nan 250014, China.
Huan Jing Ke Xue. 2017 Mar 8;38(3):1018-1027. doi: 10.13227/j.hjkx.201607201.
Farmland soils in sewage irrigation area at Longkou City were collected, soil pH together with the heavy metal content were tested. Taking 70 soil points as the study object, this paper investigated the source of heavy metals in this area based on the correlation analysis and PCA of multivariate statistical analysis theory. We studied the spatial variation and distribution characteristics about heavy metals using both the theory of geostatistics and GIS spatial interpolation method. At last, the heavy metal pollution was evaluated in the way of Nemerow Index and improved fuzzy evaluation method. It turned out that, 9 kinds of heavy metal elements in the soil of research area had a certain degree of enrichment, among them the average of Cd was 3.06 times as high as the background value, and its enrichment was most severe. The result of Nemerow Index showed that, the values of comprehensive pollution index of Cu, Cd and Pb respectively were 7.06, 6.10 and 5.54, and they all belonged to high levels of pollution. According to the results of correlation analysis and principal component analysis, Cu, Zn together with Pb, Cd were mainly affected by human factors, sewage irrigation was their common pollution factor, the pollution sources for the first two heavy metals included excessive use of chemical fertilizers and pesticides in agricultural production and the accumulation of long time, whereas pollution from northern coal mining and coal gangue piled up as well as plating, machinery manufacturing and other industrial pollution were the pollution sources of the latter two elements. Other elements (Co, Cr, Mn, Ni and As) were mainly influenced by natural factors such as parent material. Comprehensive evaluation results showed that, among the 70 points, 13 points had moderate pollution,23 points belonged to light pollution, 28 points were at alert level, 6 points were in the safe range. From the perspective of spatial distribution,high value areas of heavy metal contents were mainly concentrated in towns of Zhuyouguan and Xufu. This showed that, sewage irrigation caused a certain degree of heavy metal pollution to local soil.
采集了龙口市污水灌溉区的农田土壤,测试了土壤pH值和重金属含量。以70个土壤点位为研究对象,基于多元统计分析理论的相关性分析和主成分分析,探究了该区域重金属的来源。运用地统计学理论和GIS空间插值方法,研究了重金属的空间变异及分布特征。最后,采用内梅罗指数法和改进的模糊评价法对重金属污染进行了评价。结果表明,研究区土壤中9种重金属元素均有一定程度的富集,其中Cd平均含量是背景值的3.06倍,富集程度最为严重。内梅罗指数结果显示,Cu、Cd和Pb的综合污染指数分别为7.06、6.10和5.54,均属于重度污染。根据相关性分析和主成分分析结果,Cu、Zn与Pb、Cd主要受人为因素影响,污水灌溉是它们的共同污染因子,前两种重金属的污染源包括农业生产中化肥和农药的过量使用及长期积累,而后两种元素的污染源则是北部煤矿开采和煤矸石堆放以及电镀、机械制造等工业污染。其他元素(Co、Cr、Mn、Ni和As)主要受成土母质等自然因素影响。综合评价结果表明,70个点位中,13个点位为中度污染,23个点位为轻度污染,28个点位处于警戒水平,6个点位处于安全范围。从空间分布来看,重金属含量高值区主要集中在诸由观镇和徐福镇。这表明,污水灌溉对当地土壤造成了一定程度的重金属污染。