Galvão Nierlly, Vasconcelos Getúlio, Pessoa Rodrigo, Machado João, Guerino Marciel, Fraga Mariana, Rodrigues Bruno, Camus Julien, Djouadi Abdou, Maciel Homero
Centro de Ciência e Tecnologia de Plasmas e Materiais-PlasMat, Instituto Tecnológico de Aeronáutica, 12228-900 São José dos Campos, SP, Brazil.
Photonics Division, Instituto de Estudos Avançados, Rodovia dos Tamoios, 12228-001 São Jose dos Campos, SP, Brazil.
Materials (Basel). 2018 Jun 30;11(7):1120. doi: 10.3390/ma11071120.
This article reports a novel and efficient method to synthesize graphene using a thermal decomposition process. In this method, silicon carbide (SiC) thin films grown on Si(100) wafers with an AlN buffer layer were used as substrates. CO₂ laser beam heating, without vacuum or controlled atmosphere, was applied for SiC thermal decomposition. The physical, chemical, morphological, and electrical properties of the laser-produced graphene were investigated for different laser energy densities. The results demonstrate that graphene was produced in the form of small islands with quality, density, and properties depending on the applied laser energy density. Furthermore, the produced graphene exhibited a sheet resistance characteristic similar to graphene grown on mono-crystalline SiC wafers, which indicates its potential for electronic device applications.
本文报道了一种利用热分解过程合成石墨烯的新颖且高效的方法。在该方法中,将生长在带有AlN缓冲层的Si(100) 晶圆上的碳化硅(SiC)薄膜用作衬底。在无真空或可控气氛的情况下,采用CO₂激光束加热进行SiC热分解。针对不同的激光能量密度,研究了激光制备的石墨烯的物理、化学、形态和电学性质。结果表明,石墨烯以小岛的形式生成,其质量、密度和性质取决于所施加的激光能量密度。此外,所制备的石墨烯表现出与生长在单晶硅碳化硅晶圆上的石墨烯相似的薄层电阻特性,这表明其在电子器件应用方面具有潜力。