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氦离子光刻图形化石墨烯三角形的近场成像。

Near-field imaging of graphene triangles patterned by helium ion lithography.

机构信息

The Key Laboratory of Weak-Light Nonlinear Photonics, Ministry of Education, School of Physics and TEDA Applied Physics Institute, Nankai University, Tianjin 300457, People's Republic of China.

出版信息

Nanotechnology. 2018 Sep 21;29(38):385205. doi: 10.1088/1361-6528/aad0b4. Epub 2018 Jul 3.

DOI:10.1088/1361-6528/aad0b4
PMID:29968574
Abstract

Plasmon nanoresonators in graphene have many applications in biosensing, photodetectors and modulators. As a result, an efficient and precise patterning technique for graphene is required. Helium ion lithography (HIL) emerges as a promising tool for direct writing fabrication because it owns improved fabrication precision compared to electron beam lithography and conventional gallium focused ion beam technique. In this paper, utilizing HIL, a set of graphene triangles are patterned and excellent plasmon response is detected. Particularly, the evolution of breathing mode in these structures is unveiled by scattering-type scanning near-field optical microscopy. Besides, the plasmon response of graphene structures can be efficiently tuned by adjusting the irradiated ion dose during the etching process, which can be explained by the phenomenal simulation model. Our work demonstrates that HIL is a feasible way for precise plasmonic nanostructure fabrication, and can be applied to graphene plasmon control at the nanoscale as well.

摘要

在石墨烯中的等离激元纳米谐振器在生物传感、光探测器和调制器中有许多应用。因此,需要一种高效、精确的石墨烯图案化技术。氦离子光刻(HIL)作为一种有前途的直写制造工具出现,因为它与电子束光刻和传统的镓聚焦离子束技术相比,具有更高的制造精度。在本文中,利用 HIL 对一组石墨烯三角形进行了图案化,并检测到了优异的等离子体响应。特别地,通过散射型近场光学显微镜揭示了这些结构中呼吸模式的演化。此外,通过调整刻蚀过程中的辐照离子剂量,可以有效地调整石墨烯结构的等离子体响应,这可以通过现象模拟模型来解释。我们的工作表明,HIL 是一种用于精确等离子体纳米结构制造的可行方法,并且可以应用于纳米尺度的石墨烯等离子体控制。

相似文献

1
Near-field imaging of graphene triangles patterned by helium ion lithography.氦离子光刻图形化石墨烯三角形的近场成像。
Nanotechnology. 2018 Sep 21;29(38):385205. doi: 10.1088/1361-6528/aad0b4. Epub 2018 Jul 3.
2
Precision cutting and patterning of graphene with helium ions.氦离子对石墨烯的精确切割和图案化。
Nanotechnology. 2009 Nov 11;20(45):455301. doi: 10.1088/0957-4484/20/45/455301. Epub 2009 Oct 13.
3
In-Plane Electrical Connectivity and Near-Field Concentration of Isolated Graphene Resonators Realized by Ion Beams.离子束实现的孤立石墨烯谐振器的面内电连通和近场集中。
Adv Mater. 2017 Aug;29(30). doi: 10.1002/adma.201701083. Epub 2017 Jun 12.
4
Self-assembly and nanosphere lithography for large-area plasmonic patterns on graphene.用于石墨烯上大面积等离子体图案的自组装和纳米球光刻技术。
J Colloid Interface Sci. 2015 Jun 1;447:202-10. doi: 10.1016/j.jcis.2014.11.007. Epub 2014 Nov 11.
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Direct and reliable patterning of plasmonic nanostructures with sub-10-nm gaps.采用亚 10nm 间隔的直接且可靠的等离子体纳米结构图案化。
ACS Nano. 2011 Sep 27;5(9):7593-600. doi: 10.1021/nn2025868. Epub 2011 Aug 22.
6
Toward plasmonics with nanometer precision: nonlinear optics of helium-ion milled gold nanoantennas.朝着纳米精度的等离子体学迈进:氦离子铣削金纳米天线的非线性光学。
Nano Lett. 2014 Aug 13;14(8):4778-84. doi: 10.1021/nl5019589. Epub 2014 Jul 25.
7
Reaching the theoretical resonance quality factor limit in coaxial plasmonic nanoresonators fabricated by helium ion lithography.氦离子光刻制备的同轴等离子体纳米谐振器达到理论共振品质因子极限。
Nano Lett. 2013 Jun 12;13(6):2687-91. doi: 10.1021/nl400844a. Epub 2013 May 1.
8
Plasmonic films based on colloidal lithography.基于胶体光刻的等离子体膜。
Adv Colloid Interface Sci. 2014 Apr;206:5-16. doi: 10.1016/j.cis.2013.11.010. Epub 2013 Nov 23.
9
Experimental observed plasmon near-field response in isolated suspended graphene resonators.实验观测到孤立悬浮石墨烯谐振器中的等离子体近场响应。
Nanotechnology. 2019 Dec 13;30(50):505201. doi: 10.1088/1361-6528/ab4249. Epub 2019 Sep 6.
10
Chemically-doped graphene with improved surface plasmon characteristics: an optical near-field study.掺杂化学物质的石墨烯具有改善的表面等离子体特性:光学近场研究。
Nanoscale. 2016 Oct 7;8(37):16621-30. doi: 10.1039/c6nr04239b. Epub 2016 Aug 9.

引用本文的文献

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Sci Rep. 2025 Jul 4;15(1):23910. doi: 10.1038/s41598-025-08895-2.
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A terahertz near-field nanoscopy revealing edge fringes with a fast and highly sensitive quantum-well photodetector.一种利用快速且高灵敏度量子阱光电探测器揭示边缘条纹的太赫兹近场纳米显微镜。
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A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope.
利用氦离子显微镜对缺陷工程、离子注入和纳米加工的综述。
Beilstein J Nanotechnol. 2021 Jul 2;12:633-664. doi: 10.3762/bjnano.12.52. eCollection 2021.