Hubei Key Laboratory of Drug Synthesis and Optimization, Jingchu University of Technology, Hubei 448000, China.
Dalton Trans. 2018 Jul 24;47(29):9579-9584. doi: 10.1039/c8dt02134a.
Catalytic hydroboration of ketones with pinacolborane was achieved with a 2D iron(ii) coordination polymer (CP) of a divergent 4,2';6',4''-terpyridine (tpy) derivative under mild conditions with high efficiency. This solid iron catalyst system is more active towards the hydroboration of ketones than that of aldehydes, displaying a different trend of reactivity from known homogeneous iron hydroboration catalysts.
二茂铁(ii)配位聚合物（CP）在温和条件下高效催化酮与频哪醇硼烷的加氢硼化反应，该 CP 是由发散的 4,2';6',4''-三联吡啶（tpy）衍生物合成的。该固载铁催化剂体系对酮的加氢硼化反应比醛更具活性，表现出与已知均相铁加氢硼化催化剂不同的反应趋势。
