芳烃受限的芳烃非定向C-H活化
Arene-Limited Nondirected C-H Activation of Arenes.
作者信息
Wedi Philipp, van Gemmeren Manuel
机构信息
Max Planck Institute for Chemical Energy Conversion, Stiftstraße 34-36, 45470, Mülheim an der Ruhr, Germany.
Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße 40, 48149, Münster, Germany.
出版信息
Angew Chem Int Ed Engl. 2018 Oct 1;57(40):13016-13027. doi: 10.1002/anie.201804727. Epub 2018 Sep 11.
The nondirected C(sp )-H activation of simple arenes has advanced significantly in recent years through the discovery of new catalyst systems that are able to perform transformations with the arene as the limiting reagent. Important developments in catalyst and ligand design that have improved reactivity and selectivity are reviewed.
近年来，通过发现能够以芳烃作为限量试剂进行转化的新型催化剂体系，简单芳烃的非定向C(sp) -H活化取得了显著进展。本文综述了在催化剂和配体设计方面的重要进展，这些进展提高了反应活性和选择性。
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