Facultad de Ingeniería, Universidad Nacional de Río Cuarto, Río Cuarto, Argentina.
Química Biológica, Facultad de Ciencias Agropecuarias, Universidad Nacional de Córdoba, Córdoba, Argentina.
J Sci Food Agric. 2019 Jan 30;99(2):877-884. doi: 10.1002/jsfa.9258. Epub 2018 Aug 28.
Raya liver deodorized oil contains high concentrations of eicosapentaenoic acid (EPA), docosapentaenoic acid (DPA) and docosahexaenoic acid (DHA). The present study investigated the processes of urea complexation (UC) and molecular distillation (MD) to determine the most adequate operation conditions for each process, separately and together, aiming to obtain highly concentrated EPA, DPA and DHA ethyl esters with chemical indicator values permitted by the current legislation for edible oils.
In the second stage of MD, a concentration of 820.27 g kg in the distillate and 951.06 g kg of omega-3 fatty acid ethyl esters in the residue was obtained. The distillate showed values of free fatty acids, peroxide and p-anisidine lower than the maximum allowed for edible oils in accordance with the current legislation.
The use of UC and MD together has revealed a significant improvement in the total concentration of omega-3 fatty acid ethyl esters in the final product and good application prospects. © 2018 Society of Chemical Industry.
利肝德去味油含有高浓度的二十碳五烯酸 (EPA)、二十二碳五烯酸 (DPA) 和二十二碳六烯酸 (DHA)。本研究考察了尿素络合 (UC) 和分子蒸馏 (MD) 过程,以确定每个过程的最佳操作条件,分别和联合使用,目的是获得高浓度的 EPA、DPA 和 DHA 乙酯,其化学指标值符合现行食用油脂法规的要求。
在 MD 的第二阶段,在馏出物中获得了 820.27 g kg 的浓度,在残渣中获得了 951.06 g kg 的 ω-3 脂肪酸乙酯。馏出物的游离脂肪酸、过氧化物和对茴香胺值均低于现行法规规定的食用油脂的最大允许值。
UC 和 MD 的联合使用显著提高了最终产品中 ω-3 脂肪酸乙酯的总浓度,具有良好的应用前景。© 2018 英国化学学会。