Reduced Graphene Oxide and Its Modifications as Catalyst Supports and Catalyst Layer Modifiers for PEMFC.

Reduced graphene oxide (RGO) and RGO modified by ozone (RGO-O) and fluorine (RGO-F) were synthesized. Pt nanoparticles were deposited on these materials and also on Vulcan XC-72 using the polyol method. The structural and electrochemical properties of the obtained catalysts were investigated in a model glass three-electrode electrochemical cell and in a laboratory PEM fuel cell. Among the RGO-based catalysts, the highest electrochemically active surface area (EASA) was obtained for the oxidized RGO supported catalyst. The EASA of the fluorine-modified RGO-supported catalyst was half as big. In the PEM fuel cell the performance of RGO-based catalysts did not exceed the activity of Vulcan XC-72-based catalysts. However, the addition of an RGO-O-based catalyst to Vulcan XC-72-based catalyst (in contrast to the RGO-F-based catalyst) allowed us to increase the catalyst layer activity and PEM fuel cell performance. Possible reasons for such an effect are discussed.