混合铀氧化物价带电子结构的变化趋势。
Trends in the valence band electronic structures of mixed uranium oxides.
机构信息
Rossendorf Beamline at ESRF - The European Synchrotron, CS40220, 38043 Grenoble Cedex 9, France.
出版信息
Chem Commun (Camb). 2018 Aug 28;54(70):9757-9760. doi: 10.1039/c8cc05464a.
PMID:30109321
Abstract
The valence band electronic structures of mixed uranium oxides (UO2, U4O9, U3O7, U3O8, and β-UO3) have been studied using the resonant inelastic X-ray scattering (RIXS) technique at the U M5 edge and computational methods. We show here that the RIXS technique and recorded U 5f-O 2p charge transfer excitations can be used to test the validity of theoretical approximations.
摘要
混合铀氧化物（UO2、U4O9、U3O7、U3O8 和 β-UO3）的价带电子结构已通过共振非弹性 X 射线散射（RIXS）技术在 U M5 边缘和计算方法进行了研究。我们在此表明，RIXS 技术和记录的 U 5f-O 2p 电荷转移激发可用于检验理论近似的有效性。
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