双膦酚和酚盐配合物的 Mn(i)：锰(i)催化的蒂希琴纳反应。
Bisphosphine phenol and phenolate complexes of Mn(i): manganese(i) catalyzed Tishchenko reaction.
机构信息
Department of Chemistry, University at Buffalo, State University of New York, Buffalo, New York 14260, USA.
出版信息
Dalton Trans. 2018 Sep 18;47(36):12652-12655. doi: 10.1039/c8dt02933d.
PMID:30124698
Abstract
We synthesized new organomanganese complexes using the phenolic "pincer" type ligand H-POP. The coordination chemistry of H-POP with Mn(i) was explored, revealing a wide range of binding motifs. Finally, we found that complex 1 catalyzes the formation of benzyl benzoate from benzaldehyde in a Tishchenko reaction.
摘要
我们使用酚类“夹钳”型配体 H-POP 合成了新的有机锰配合物。研究了 H-POP 与 Mn(i)的配位化学，揭示了广泛的结合模式。最后，我们发现配合物 1 可以在 Tishchenko 反应中催化苯甲醛形成苯甲酸苄酯。
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