Wang Jie, Li Meisheng, Qian Ming, Zhou Shouyong, Xue Ailian, Zhang Lili, Zhao Yijiang, Xing Weihong
Jiangsu Engineering Laboratory for Environmental Functional Materials, Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, No.111 West Changjiang Road, Huaian, 223300, Jiangsu Province, People's Republic of China.
College of Chemical Engineering, Nanjing Tech University, No.5 Xinmofan Road, Nanjing, 210009, Jiangsu Province, People's Republic of China.
Nanoscale Res Lett. 2018 Aug 22;13(1):248. doi: 10.1186/s11671-018-2654-7.
TMC-incorporated carbon nitride (CN) with hexagonal and quadrangle honeycomb-like structure and having periodic lattice defects linked by -CONH- bond was synthesized through combining the high calcination with the chemical condensation of melamine and 1,3,5-benzenetricarbonyl trichloride. The obtained CN has a tri-s-triazine ring and benzene ring skeleton, which makes it have excellent mechanical and thermal stability. The BET specific surface area was enhanced to about 125.6 m/g, and the mean pore size is about 3.43 nm. This CN exhibited an excellent adsorption-enhanced photocatalytic performance.
通过三聚氰胺与1,3,5-苯三甲酰氯的化学缩合结合高温煅烧，合成了具有六边形和四边形蜂窝状结构且具有由-CONH-键连接的周期性晶格缺陷的TMC掺杂氮化碳（CN）。所得的CN具有三嗪环和苯环骨架，使其具有优异的机械和热稳定性。BET比表面积提高到约125.6 m²/g，平均孔径约为3.43 nm。这种CN表现出优异的吸附增强光催化性能。
