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脱脂牛奶以及超滤/渗滤截留物的pH值变化对乳蛋白浓缩物(MPC70)粉末特性的影响。

Effect of change in pH of skim milk and ultrafiltered/diafiltered retentates on milk protein concentrate (MPC70) powder properties.

作者信息

Meena Ganga Sahay, Singh Ashish Kumar, Gupta Vijay Kumar, Borad Sanket, Parmar Pankaj T

机构信息

Dairy Technology Division, ICAR-National Dairy Research Institute, Karnal, 132001 India.

出版信息

J Food Sci Technol. 2018 Sep;55(9):3526-3537. doi: 10.1007/s13197-018-3278-8. Epub 2018 Jun 18.

Abstract

Poor solubility of milk protein concentrate (MPC) powders are attributed to their high protein and calcium contents. Concentration of skim milk in ultrafiltration (UF) and diafiltration (DF) increased total solids, protein and mineral contents and changed pH and ζ-potential values of the retentates that leads to milk proteins destabilization in 7× UF/DF retentates. Hence, this investigation was aimed to study the effect of change in pH of skim milk (no change; native pH maintained) and DF retentates (5.85 and 7.10) with KOH, NaOH and NaHPO∙2HO on physicochemical, reconstitution, functional and rheological properties of fresh MPC70 powders. MPC70-7.10 powder had significantly higher (< 0.05) solubility, but MPC70-NaOH and MPC70-5.85 showed significantly lower solubility than control. However, after two months storage at 25 ± 1 °C, control powder had significantly lower solubility (27.78% decrease) than treated powders. These changes in pH, significantly decreased calcium content and specific surface area; significantly improved viscosity, water binding, oil binding, emulsifying, foaming and buffering capacities, flowability, pH (except MPC70-5.85) and packed bulk density (except MPC70-NaOH) of treated powders over control. However, rennet coagulation time of all reconstituted powder solutions was similar. Hershel Bulkley, a best fit model, efficiently explained the pseudoplastic rheological behavior of all reconstituted MPC70 powders. This investigation had established that change in pH could improve the functional properties of MPC70 powders and is a simple, cheap, compatible and easy to use approach. Treated MPC70 powders could replace control in several food formulations owing to their improved functional properties.

摘要

乳蛋白浓缩物(MPC)粉末的低溶解度归因于其高蛋白和钙含量。超滤(UF)和渗滤(DF)过程中脱脂乳的浓缩增加了总固体、蛋白质和矿物质含量,并改变了截留物的pH值和ζ电位值,导致7倍超滤/渗滤截留物中的乳蛋白不稳定。因此,本研究旨在研究用氢氧化钾、氢氧化钠和磷酸氢二钠将脱脂乳(无变化;保持天然pH值)和渗滤截留物(5.85和7.10)的pH值改变对新鲜MPC70粉末的物理化学、复溶、功能和流变学性质的影响。MPC70 - 7.10粉末的溶解度显著更高(<0.05),但MPC70 - 氢氧化钠和MPC70 - 5.85的溶解度显著低于对照。然而,在25±1°C下储存两个月后,对照粉末的溶解度显著低于处理后的粉末(降低了27.78%)。这些pH值的变化显著降低了钙含量和比表面积;与对照相比,显著提高了处理后粉末的粘度、水结合能力、油结合能力、乳化能力、发泡能力和缓冲能力、流动性、pH值(MPC70 - 5.85除外)和堆积密度(MPC70 - 氢氧化钠除外)。然而,所有复溶粉末溶液的凝乳酶凝固时间相似。Hershel Bulkley是一个最佳拟合模型,有效地解释了所有复溶MPC70粉末的假塑性流变行为。本研究表明,pH值的改变可以改善MPC70粉末的功能性质,是一种简单、廉价、兼容且易于使用的方法。由于其改善的功能性质,处理后的MPC70粉末可以在几种食品配方中替代对照。

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