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具有基于电纺纳米纤维毡对电极的染料敏化太阳能电池。

Dye-Sensitized Solar Cells with Electrospun Nanofiber Mat-Based Counter Electrodes.

作者信息

Juhász Junger Irén, Wehlage Daria, Böttjer Robin, Grothe Timo, Juhász László, Grassmann Carsten, Blachowicz Tomasz, Ehrmann Andrea

机构信息

Faculty of Engineering and Mathematics, Bielefeld University of Applied Sciences, 33619 Bielefeld, Germany.

Faculty of Electrical Engineering, Media Technology and Computer Science, Deggendorf Institute of Technology, 94469 Deggendorf, Germany.

出版信息

Materials (Basel). 2018 Sep 4;11(9):1604. doi: 10.3390/ma11091604.


DOI:10.3390/ma11091604
PMID:30181451
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6163651/
Abstract

Textile-based dye-sensitized solar cells (DSSCs) can be created by building the necessary layers on a textile fabric or around fibers which are afterwards used to prepare a textile layer, typically by weaving. Another approach is using electrospun nanofiber mats as one or more layers. In this work, electrospun polyacrylonitrile (PAN) nanofiber mats coated by a conductive polymer poly(3,4-ethylenedioxythiopene) polystyrene sulfonate (PEDOT:PSS) were used to produce the counter electrodes for half-textile DSSCs. The obtained efficiencies were comparable with the efficiencies of pure glass-based DSSCs and significantly higher than the efficiencies of DSSCs with cotton based counter electrodes. The efficiency could be further increased by increasing the number of PEDOT:PSS layers on the counter electrode. Additionally, the effect of the post treatment of the conductive layers by HCl, acetic acid, or dimethyl sulfoxide (DMSO) on the DSSC efficiencies was investigated. Only the treatment by HCl resulted in a slight improvement of the energy-conversion efficiency.

摘要

基于纺织品的染料敏化太阳能电池(DSSC)可以通过在织物上或围绕纤维构建必要的层来制造,随后通常通过编织来制备纺织层。另一种方法是使用电纺纳米纤维垫作为一层或多层。在这项工作中,用导电聚合物聚(3,4 - 乙撑二氧噻吩)聚苯乙烯磺酸盐(PEDOT:PSS)涂覆的电纺聚丙烯腈(PAN)纳米纤维垫被用于制造半纺织DSSC的对电极。获得的效率与纯玻璃基DSSC的效率相当,并且显著高于具有棉基对电极的DSSC的效率。通过增加对电极上PEDOT:PSS层的数量,效率可以进一步提高。此外,还研究了用盐酸、乙酸或二甲基亚砜(DMSO)对导电层进行后处理对DSSC效率的影响。只有用盐酸处理导致能量转换效率略有提高。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/26d1628fd05a/materials-11-01604-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/abf2477f9756/materials-11-01604-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/dca43b5c75b1/materials-11-01604-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/d72aa85dabde/materials-11-01604-g003a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/aabc1d21018d/materials-11-01604-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/64676f40a2d0/materials-11-01604-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/c3379d73e555/materials-11-01604-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/26d1628fd05a/materials-11-01604-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/abf2477f9756/materials-11-01604-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/dca43b5c75b1/materials-11-01604-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/d72aa85dabde/materials-11-01604-g003a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/aabc1d21018d/materials-11-01604-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/64676f40a2d0/materials-11-01604-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/c3379d73e555/materials-11-01604-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/25de/6163651/26d1628fd05a/materials-11-01604-g007.jpg

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[1]
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[2]
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[4]
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[5]
Cause, Regulation and Utilization of Dye Aggregation in Dye-Sensitized Solar Cells.

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[6]
Novel Smart Textiles.

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[7]
Conductive Electrospun Nanofiber Mats.

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[8]
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[9]
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[10]
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本文引用的文献

[1]
Fixing PAN Nanofiber Mats during Stabilization for Carbonization and Creating Novel Metal/Carbon Composites.

Polymers (Basel). 2018-7-4

[2]
Spectral Analysis and Parameter Identification of Textile-Based Dye-Sensitized Solar Cells.

Materials (Basel). 2018-9-5

[3]
Porphyrin-Based Dye-Sensitized Solar Cells (DSSCs): a Review.

J Fluoresc. 2017-5

[4]
PEDOT:PSS "Wires" Printed on Textile for Wearable Electronics.

ACS Appl Mater Interfaces. 2016-10-12

[5]
PEDOT:PSS Films with Metallic Conductivity through a Treatment with Common Organic Solutions of Organic Salts and Their Application as a Transparent Electrode of Polymer Solar Cells.

ACS Appl Mater Interfaces. 2016-5-2

[6]
Highly-efficient dye-sensitized solar cells with collaborative sensitization by silyl-anchor and carboxy-anchor dyes.

Chem Commun (Camb). 2015-11-14

[7]
Preparation and characterization of electrospun PLCL/Poloxamer nanofibers and dextran/gelatin hydrogels for skin tissue engineering.

PLoS One. 2014-11-18

[8]
Porphyrins as excellent dyes for dye-sensitized solar cells: recent developments and insights.

Dalton Trans. 2015-1-14

[9]
Highly flexible dye-sensitized solar cells produced by sewing textile electrodes on cloth.

Sci Rep. 2014-6-24

[10]
Wearable solar cells by stacking textile electrodes.

Angew Chem Int Ed Engl. 2014-4-30

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