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聚3,4-乙撑二氧噻吩：聚苯乙烯磺酸盐作为对电极与聚3,4-乙撑二氧噻吩：卡拉胶作为电解质在染料敏化太阳能电池应用中的不同作用：一项系统文献综述

Different Roles between PEDOT:PSS as Counter Electrode and PEDOT:Carrageenan as Electrolyte in Dye-Sensitized Solar Cell Applications: A Systematic Literature Review.

作者信息

Nurazizah Euis Siti, Aprilia Annisa, Risdiana Risdiana, Safriani Lusi

机构信息

Department of Physics, Faculty of Mathematics and Natural Science, Universitas Padjadjaran, Jl. Raya Bandung-Sumedang KM 21, Sumedang 45363, Indonesia.

出版信息

Polymers (Basel). 2023 Jun 18;15(12):2725. doi: 10.3390/polym15122725.

DOI:10.3390/polym15122725
PMID:37376370
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10302568/
Abstract

Poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) has been mostly used as a counter electrode to give a high performance of dye-sensitized solar cell (DSSC). Recently, PEDOT doped by carrageenan, namely PEDOT:Carrageenan, was introduced as a new material to be applied on DSSC as an electrolyte. PEDOT:Carrageenan has a similar synthesis process as PEDOT:PSS, owing to their similar ester sulphate (-SOH) groups in both PSS and carrageenan. This review provides an overview of the different roles between PEDOT:PSS as a counter electrode and PEDOT:Carrageenan as an electrolyte for DSSC applications. The synthesis process and characteristics of PEDOT:PSS and PEDOT:Carrageenan were also described in this review. In conclusion, we found that the primary role of PEDOT:PSS as a counter electrode is to transfer electrons back to cell and accelerate redox reaction with its superior electrical conductivity and high electrocatalytic activity. PEDOT:Carrageenan as an electrolyte has not shown the main role for regenerating the dye sensitized at the oxidized state, probably due to its low ionic conductivity. Therefore, PEDOT:Carrageenan still obtained a low performance of DSSC. Additionally, the future perspective and challenges of using PEDOT:Carrageenan as both electrolyte and counter electrode are described in detail.

摘要

聚（3,4-乙撑二氧噻吩）：聚苯乙烯磺酸盐（PEDOT:PSS）主要用作对电极以实现高性能的染料敏化太阳能电池（DSSC）。最近，由角叉菜胶掺杂的PEDOT，即PEDOT:角叉菜胶，作为一种新型材料被引入用于DSSC作为电解质。PEDOT:角叉菜胶具有与PEDOT:PSS相似的合成过程，这是由于它们在PSS和角叉菜胶中都有相似的硫酸酯（-SOH）基团。本综述概述了PEDOT:PSS作为对电极与PEDOT:角叉菜胶作为DSSC应用电解质之间的不同作用。本综述还描述了PEDOT:PSS和PEDOT:角叉菜胶的合成过程及特性。总之，我们发现PEDOT:PSS作为对电极的主要作用是将电子转移回电池并以其优异的导电性和高电催化活性加速氧化还原反应。PEDOT:角叉菜胶作为电解质在再生处于氧化态的染料敏化方面未显示出主要作用，这可能是由于其低离子电导率。因此，PEDOT:角叉菜胶的DSSC性能仍然较低。此外，还详细描述了将PEDOT:角叉菜胶用作电解质和对电极的未来前景及挑战。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/df0358aacbd5/polymers-15-02725-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/f9a5dc95c471/polymers-15-02725-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/70e15733a039/polymers-15-02725-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/1179e9c8161f/polymers-15-02725-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/e11fb62820cf/polymers-15-02725-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/6f9240cce6de/polymers-15-02725-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/47b9a3318ed8/polymers-15-02725-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/f2e3909831e2/polymers-15-02725-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/df0358aacbd5/polymers-15-02725-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/f9a5dc95c471/polymers-15-02725-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/70e15733a039/polymers-15-02725-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/1179e9c8161f/polymers-15-02725-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/e11fb62820cf/polymers-15-02725-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/6f9240cce6de/polymers-15-02725-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/47b9a3318ed8/polymers-15-02725-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/f2e3909831e2/polymers-15-02725-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b7d/10302568/df0358aacbd5/polymers-15-02725-g008.jpg

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RSC Adv. 2019 Feb 21;9(11):6363-6378. doi: 10.1039/c8ra08801b. eCollection 2019 Feb 18.
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Stretchable Conductive Polymers and Composites Based on PEDOT and PEDOT:PSS.基于 PEDOT 和 PEDOT:PSS 的可拉伸导电聚合物和复合材料。
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Chem Soc Rev. 2017 Oct 2;46(19):5975-6023. doi: 10.1039/c6cs00752j.
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Structural control of mixed ionic and electronic transport in conducting polymers.导电聚合物中离子与电子混合传输的结构控制
Nat Commun. 2016 Apr 19;7:11287. doi: 10.1038/ncomms11287.
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The structure of kappa/iota-hybrid carrageenans II. Coil-helix transition as a function of chain composition.κ/ι-杂化角叉菜胶的结构II. 作为链组成函数的螺旋-卷曲转变
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