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花色苷-3-葡萄糖苷的脂肪酸酶酰化对其颜色稳定性的改善。

Improvement of the Color Stability of Cyanidin-3-glucoside by Fatty Acid Enzymatic Acylation.

机构信息

REQUIMTE/LAQV, Departamento de Química e Bioquímica, Faculdade de Ciências , Universidade do Porto , Rua do Campo Alegre, 687 , 4169-007 Porto , Portugal.

出版信息

J Agric Food Chem. 2018 Sep 26;66(38):10003-10010. doi: 10.1021/acs.jafc.8b03536. Epub 2018 Sep 18.

Abstract

Anthocyanins are water-soluble pigments with limited application in lipophilic matrices such as lipid-based foods and cosmetic formulations. In this work, the liposolubility improvement of cyanidin-3-glucoside (cy3glc) was performed by enzymatic esterification with saturated fatty acids with variable chain lengths, and their thermostabilities were evaluated at different pH values in a lipophilic medium (an aqueous sodium dodecyl sulfate solution) by means of UV-vis spectroscopy. Overall, lipophilic cy3glc derivatives showed improved color stability and lowered sensitivity to thermal degradation than nonmodified cy3glc in an SDS micellar solution between pH 3 and 7.

摘要

花色苷是一种水溶性色素,在脂溶性基质(如含脂类的食物和化妆品配方)中的应用有限。在这项工作中,通过用具有不同链长的饱和脂肪酸对矢车菊素-3-葡萄糖苷(cy3glc)进行酶酯化,提高了其脂溶性,并通过紫外可见光谱在脂相介质(十二烷基硫酸钠水溶液)中不同 pH 值下评估了它们的热稳定性。总的来说,与未修饰的 cy3glc 相比,在 SDS 胶束溶液的 pH 3 到 7 之间,脂溶性 cy3glc 衍生物具有更好的颜色稳定性和更低的热降解敏感性。

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