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大直径钴纳米线与纳米管磁性的比较研究

A Comparative Study of Magnetic Properties of Large Diameter Co Nanowires and Nanotubes.

作者信息

Fernandez-Roldan Jose Angel, Chrischon Dieivase, Dorneles Lucio Strazzabosco, Chubykalo-Fesenko Oksana, Vazquez Manuel, Bran Cristina

机构信息

Instituto de Ciencia de Materiales de Madrid, CSIC, 28049 Madrid, Spain.

Physics department, Federal University of Santa Maria, RS 97105-900, Brazil.

出版信息

Nanomaterials (Basel). 2018 Sep 6;8(9):692. doi: 10.3390/nano8090692.

Abstract

A comparative study of the magnetic properties of the arrays of Co nanowires and nanotubes with large external diameters (180 nm) has been carried out. The nanowires/nanotubes were grown by electrodeposition into the self-assembled pores of anodic alumina membranes. The experimental study of their magnetic behavior was focused on the angular dependence of hysteresis loops and their parameters. In both nanowire and nanotube arrays, from the analysis of experimental data, effective longitudinal magnetic anisotropy is concluded, which is stronger in the case of the nanotube array. In addition, the extremely small remanence observed for all loops indicates the important role played by magnetostatic interactions. Micromagnetic simulations were first performed considering intrinsic shape and magnetocrystalline anisotropy terms, together with an effective easy-plane anisotropy to account for those magnetostatic interactions. A qualitative agreement between experiments and simulations is found despite the complexity introduced by the intrinsic and extrinsic array properties (i.e., large diameters, grain structure, and array configuration). In addition, simulations were also carried out for individual nanowire/nanotube with a particular emphasis to understand their differences at the remanence, due to pure geometry contribution.

摘要

对具有大外径(180纳米)的钴纳米线和纳米管阵列的磁性进行了一项对比研究。通过电沉积将纳米线/纳米管生长到阳极氧化铝膜的自组装孔中。对其磁行为的实验研究集中在磁滞回线的角度依赖性及其参数上。在纳米线和纳米管阵列中,通过对实验数据的分析,得出了有效的纵向磁各向异性,在纳米管阵列的情况下更强。此外,所有回线中观察到的极小剩磁表明静磁相互作用起到了重要作用。首先进行了微磁模拟,考虑了固有形状和磁晶各向异性项,以及一种有效的易平面各向异性来解释那些静磁相互作用。尽管固有和外在阵列特性(即大直径、晶粒结构和阵列构型)引入了复杂性,但实验和模拟之间仍发现了定性的一致性。此外,还对单个纳米线/纳米管进行了模拟,特别强调了由于纯几何贡献而在剩磁方面的差异。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e9f3/6164415/d109aea833ae/nanomaterials-08-00692-g001.jpg

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