Das Deepankar, Mal Rudrajit, Mittal Nisha, Zhu Zhengbo, Emge Thomas J, Seidel Daniel
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, NJ 08854, USA.
Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611, USA.
Beilstein J Org Chem. 2018 Aug 1;14:2002-2011. doi: 10.3762/bjoc.14.175. eCollection 2018.
Chiral bisoxazoline ligands containing naphthyridine, pyridazine, pyrazole, and phenol bridging units were prepared and shown to form bimetallic complexes with various metal salts. X-ray crystal structures of bis-nickel naphthyridine-bridged, bis-zinc pyridazine-bridged, and bis-nickel as well as bis-palladium pyrazole-bridged complexes were obtained.
制备了含有萘啶、哒嗪、吡唑和苯酚桥连单元的手性双恶唑啉配体,并证明它们能与各种金属盐形成双金属配合物。获得了萘啶桥连双镍、哒嗪桥连双锌、吡唑桥连双镍以及吡唑桥连双钯配合物的X射线晶体结构。