Bénichou O, Illien P, Oshanin G, Sarracino A, Voituriez R
Sorbonne Université, CNRS, Laboratoire de Physique Théorique de la Matière Condensée (UMR 7600), 4 Place Jussieu, 75252 Paris Cedex 05, France.
J Phys Condens Matter. 2018 Nov 7;30(44):443001. doi: 10.1088/1361-648X/aae13a. Epub 2018 Sep 13.
We summarise different results on the diffusion of a tracer particle in lattice gases of hard-core particles with stochastic dynamics, which are confined to narrow channels-single-files, comb-like structures and quasi-one-dimensional channels with the width equal to several particle diameters. We show that in such geometries a surprisingly rich, sometimes even counter-intuitive, behaviour emerges, which is absent in unbounded systems. This is well-documented for the anomalous diffusion in single-files. Less known is the anomalous dynamics of a tracer particle in crowded branching single-files-comb-like structures, where several kinds of anomalous regimes take place. In narrow channels, which are broader than single-files, one encounters a wealth of anomalous behaviours in the case where the tracer particle is subject to a regular external bias: here, one observes an anomaly in the temporal evolution of the tracer particle velocity, super-diffusive at transient stages, and ultimately a giant diffusive broadening of fluctuations in the position of the tracer particle, as well as spectacular multi-tracer effects of self-clogging of narrow channels. Interactions between a biased tracer particle and a confined crowded environment also produce peculiar patterns in the out-of-equilibrium distribution of the environment particles, very different from the ones appearing in unbounded systems. For moderately dense systems, a surprising effect of a negative differential mobility takes place, such that the velocity of a biased tracer particle can be a non-monotonic function of the force. In some parameter ranges, both the velocity and the diffusion coefficient of a biased tracer particle can be non-monotonic functions of the density. We also survey different results obtained for a tracer particle diffusion in unbounded systems, which will permit a reader to have an exhaustively broad picture of the tracer diffusion in crowded environments.
我们总结了示踪粒子在具有随机动力学的硬核粒子晶格气体中的扩散的不同结果,这些硬核粒子被限制在狭窄通道中——单列、梳状结构以及宽度等于几个粒子直径的准一维通道。我们表明,在这样的几何结构中会出现令人惊讶的丰富行为,有时甚至是违反直觉的行为,而在无界系统中则不存在。这在单列中的反常扩散方面有充分记录。鲜为人知的是示踪粒子在拥挤分支单列——梳状结构中的反常动力学,其中会出现几种反常 regime。在比单列更宽的狭窄通道中,当示踪粒子受到规则外部偏置时,会遇到大量反常行为:在这里,人们观察到示踪粒子速度的时间演化中的反常现象,在瞬态阶段是超扩散的,最终示踪粒子位置的涨落会出现巨大的扩散展宽,以及狭窄通道自堵塞的壮观多示踪效应。有偏置的示踪粒子与受限拥挤环境之间的相互作用也会在环境粒子的非平衡分布中产生奇特模式,与无界系统中出现的模式非常不同。对于中等密度系统,会出现负微分迁移率的惊人效应,使得有偏置的示踪粒子的速度可以是力的非单调函数。在某些参数范围内,有偏置的示踪粒子的速度和扩散系数都可以是密度的非单调函数。我们还调查了在无界系统中示踪粒子扩散所获得的不同结果,这将使读者对拥挤环境中的示踪扩散有一个详尽广泛的了解。