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基于实测的建筑涂料挥发性有机化合物(VOCs)排放的含量水平及成分特征

[Content Levels and Compositions Characteristics of Volatile Organic Compounds(VOCs) Emission from Architectural Coatings Based on Actual Measurement].

作者信息

Gao Mei-Ping, Deng Zi-Yu, Nie Lei, Shao Xia, An Xiao-Shuan

机构信息

Beijing Key Laboratory of Urban Atmospheric Volatile Organic Compounds Pollution Control and Application, Beijing Municipal Research Institute of Environmental Protection, Beijing 100037, China.

School of Resource Environment and Tourism, Capital Normal University, Beijing 100048, China.

出版信息

Huan Jing Ke Xue. 2018 Oct 8;39(10):4414-4421. doi: 10.13227/j.hjkx.201712038.

Abstract

The content levels and composition characteristics of Volatile Organic Compounds (VOCs) from architectural coatings including interior wall coatings, exterior wall coatings, waterproofing coatings, anticorrosive coatings and floor coatings were investigated in this study. Architectural coating samples were obtained from manufacturers and retail outlets and the associated VOC contents and compositions were determined based on the domestic standard methods for measurement of VOCs in architectural coatings.The results showed that the VOC contents were 0-145 g·L and 0-171 g·L for interior and exterior wall coatings respectively. The proportion of samples that met the standards of HJ 2537-2014 were 90%, 80%, 96% and 94% for interior wall finishing coats, interior wall primary coats, exterior wall finishing coats and exterior wall primary coats respectively.The VOC content was found to be less than 10 g·L for more than 90% of polymer-cement based waterproof coatings and acrylate polymer emulsion waterproof coatings respectively, and 1-324 g·L for polyurethane waterproof coatings. The VOC contents for solvent-based coatings were found to be generally high, with VOC contents ranging from between 291-681 g·L and 16-580 g·L for solvent-based anticorrosive coatings and solvent-based floor coatings respectively, with great variation shown between different compositions and brands. The 1,2-propanediol and ethylene glycol were the most VOC in water-based coatings with methanol and 2-amino-2-methyl-1-propanol equal second. The main VOCs in solvent-based coatings were toluene, ethyl benzene, xylenes (total), ethyl acetate, butyl acetate and isobutyl acetate.

摘要

本研究调查了包括内墙涂料、外墙涂料、防水涂料、防腐涂料和地坪涂料在内的建筑涂料中挥发性有机化合物(VOCs)的含量水平和组成特征。从制造商和零售店获取建筑涂料样品,并根据国内建筑涂料中VOCs的测量标准方法测定相关的VOC含量和组成。结果表明,内墙涂料和外墙涂料的VOC含量分别为0 - 145 g·L和0 - 171 g·L。内墙面漆、内墙底漆、外墙面漆和外墙底漆符合HJ 2537 - 2014标准的样品比例分别为90%、80%、96%和94%。发现分别超过90%的聚合物水泥基防水涂料和丙烯酸酯聚合物乳液防水涂料的VOC含量低于10 g·L,聚氨酯防水涂料的VOC含量为1 - 324 g·L。溶剂型涂料的VOC含量普遍较高,溶剂型防腐涂料和溶剂型地坪涂料的VOC含量分别为291 - 681 g·L和16 - 580 g·L,不同组成和品牌之间差异很大。水性涂料中1,2 - 丙二醇和乙二醇是VOC含量最高的,甲醇和2 - 氨基 - 2 - 甲基 - 1 - 丙醇并列第二。溶剂型涂料中的主要VOCs是甲苯、乙苯、二甲苯(总量)、乙酸乙酯、乙酸丁酯和乙酸异丁酯。

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