[Source Profiles and Chemical Reactivity of Volatile Organic Compounds from Surface Coating of Aluminum Products in Foshan, China].

Volatile organic compounds (VOCs) samples were collected and analyzed for the surface coating processes of aluminum products in Foshan. The concentration levels of VOCs from solvent-based coating (63.90-149.67 mg·m) are much higher than that from water-based, electrophoretic, and powder coating (2.99-21.93 mg·m). With respect to the VOC composition, aromatics are the main VOC group of solvent-based coating emission, ranging from 52.32%-71.55%. Typical species include toluene, ethylbenzene, xylene, and ethyl acetate. The VOCs emitted from water-based coating are mainly oxygenated VOCs, such as ethyl acetate (48.59%) and tetrahydrofuran (8.43%), while the percentage of aromatics (11.32%) is lower than that of solvent-based coating. Isopropanol is the most abundant species of electrophoretic coating emissions, accounting for up to 81.19% of the VOCs. The major VOC compounds of powder coating processes are acetone (30.25%), propane (15.48%), ethylene (12.15%), ethane (9.35%), and -butane (5.16%). The calculation of the ozone formation potential (OFP) shows that the solvent-based coating has the highest OFP (3.89 g·g), followed by powder coating (2.53 g·g), while water-based and electrophoretic coating have lower OFPs (1.31 and 0.85 g·g, respectively). The most important contributor to OFP of solvent-based coating are aromatics, especially C-C aromatics. The major contributors of water-based coating are ethyl acetate, -xylenes, and toluene, with contributions of 23.24%, 21.76%, and 17.07%, respectively. The key reactive components of powder coating are ethylene, propene, and 1-butene; the sum of alkenes accounts for 71.11% of the OFP. With respect to the contribution of VOCs emitted from electrophoretic coating to the OFP, the percentage of isopropanol (65.08%) is significantly larger than that of other species (<6%).