College of Materials Science and Engineering, Nanjing Forestry University, Nanjing, 210037, China.
College of Materials Science and Engineering, Nanjing Forestry University, Nanjing, 210037, China.
Carbohydr Polym. 2018 Dec 1;201:211-217. doi: 10.1016/j.carbpol.2018.08.059. Epub 2018 Aug 18.
Deep eutectic solvent (DES) prepared from choline chloride and four organic acid were evaluated for the extraction of chitin from lobster shell. It was found that the purity of chitins extracted with DESs was related to acid used. Purity of chitin extracted with choline chloride-malonic acid was the highest. Chitins extracted through DES treatment results in various molecular weight, which is associated with type of acid and temperature used during the treatment. For instance, chitin produced by malonic acid at 50 °C and 100 °C results in molecular weight of 312 KDa and 199 KDa respectively, whereas it extracted with malic acid at 100 °C results in 91 KDa. The physicochemical properties of chitins were characterized by FTIR, XRD, TG and SEM. Moreover, the CaCO was successfully converted into levulinic acid calcium salt which could be used as calcium supplement.
从氯化胆碱和四种有机酸制备的深共晶溶剂(DES)用于从龙虾壳中提取甲壳素。结果发现,用 DES 提取的甲壳素的纯度与所用的酸有关。用氯化胆碱-丙二酸制备的甲壳素的纯度最高。通过 DES 处理提取的甲壳素具有不同的分子量,这与处理过程中使用的酸的类型和温度有关。例如,在 50°C 和 100°C 下用丙二酸生产的甲壳素的分子量分别为 312 kDa 和 199 kDa,而在 100°C 下用苹果酸提取的甲壳素的分子量为 91 kDa。通过傅里叶变换红外光谱(FTIR)、X 射线衍射(XRD)、热重分析(TG)和扫描电子显微镜(SEM)对甲壳素的理化性质进行了表征。此外,碳酸钙成功转化为可作为钙补充剂的乙酰丙酸钙盐。