Noble metal-free NiS with rich active sites loaded g-CN for highly efficient photocatalytic H evolution under visible light irradiation.

A series of noble-metal-free NiS-loaded g-CN hybrid composites were prepared via simple hydrothermal method. Benefited from the wider spectral response range and the effective separation of photoelectron-holes of g-CN-NiS heterojunction catalysts, as well as the rich unsaturated active S atoms on the NiS with S, the composite catalysts has prominent photocatalytic performance for H evolution. Remarkably, the optimal composite photocatalysts achieved an average hydrogen production rate as high as 715.83 μmol/h/g in 3 h under visible-light irradiation, which is 2.75 times as high as that of precious metal Pt (259.5 μmol/h/g) as a co-catalyst. Besides, the composite catalyst still shows prominent photocatalytic performance for H evolution after three continuous photocatalytic reaction cycles for 9 h. This study provided a facile method to build a low-cost but effective metal sulfide co-catalyst for hydrogen production under visible light irradiation.