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利用半胱氨酸修饰的硅烷涂层磁性纳米材料吸附布洛芬。

Adsorption of ibuprofen using cysteine-modified silane-coated magnetic nanomaterial.

机构信息

Department of Chemical Engineering, National Institute of Technology Karnataka, Mangalore, India.

出版信息

Environ Sci Pollut Res Int. 2019 Nov;26(33):34117-34126. doi: 10.1007/s11356-018-3272-8. Epub 2018 Oct 6.

Abstract

Industrialization and growth of the pharmaceutical companies have been a boon to the mankind in our day to day life in myriad ways. However, due to the uninhibited release of these active pharmaceutical compounds into the water systems has caused detrimental effects to the genetic pool. In this study, L-cysteine-modified 3-glycidyloxypropyltrimethoxysilane-coated magnetic nanomaterial showed a maximum removal of the efficiency of 82.90% for the nanomaterial dosage of 30 mg at an initial concentration of 50 mg L at pH 6.0. Further, the nanomaterial showed reusability efficiency up to 80% for three cycles. The adsorption kinetics follow the pseudo-second-order reaction and the adsorption isotherm model best fits the Langmuir isotherm proving the adsorption process to be a monolayer sorption on a monolayer surface. This magnetic nanomaterial could serve as a promising tool for the removal of pharmaceutical compounds from aqueous solutions. Graphical abstract ᅟ.

摘要

工业化和制药公司的发展在我们的日常生活中以无数种方式造福了人类。然而,由于这些活性药物化合物不受限制地释放到水系中,对遗传物质库造成了有害影响。在这项研究中,L-半胱氨酸修饰的 3-缩水甘油醚丙基三甲氧基硅烷涂层磁性纳米材料在初始浓度为 50mg/L、pH 值为 6.0 的条件下,纳米材料剂量为 30mg 时,显示出最大 82.90%的去除效率。此外,纳米材料在三个循环中显示出高达 80%的可重复使用效率。吸附动力学符合伪二级反应,吸附等温线模型最符合朗缪尔等温线,证明吸附过程是单层在单层表面上的吸附。这种磁性纳米材料可以作为从水溶液中去除药物化合物的有前途的工具。

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