Department of Chemistry , Northwestern University , 2145 Sheridan Road , Evanston , Illinois 60208 , United States.
Department of Chemistry, Chemical Theory Center and Minnesota Supercomputing Institute , University of Minnesota , 207 Pleasant Street Southeast , Minneapolis , Minnesota 55455 , United States.
Inorg Chem. 2018 Nov 5;57(21):13246-13251. doi: 10.1021/acs.inorgchem.8b01748. Epub 2018 Oct 9.
Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.
同结构的金属有机骨架（MOFs）可以由多种金属氧化物簇来制备，包括过渡金属、镧系元素和锕系元素。与金属氧化物节点相关的羟基的 O-H 伸缩振动频率的实验和计算位移揭示了这些单元的不同电子性质，从而为沉积在这些节点上的其他材料提供了调节支撑效应的机会。
