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封装的二氯乙烷介导的 A1/A2 - 二羟基 - 辛氧基柱[5]芳烃 1,2 - 二氯乙烷单溶剂化物的互锁超分子聚合物组装体

Encapsulated di-chloro-ethane-mediated inter-locked supra-molecular polymeric assembly of A1/A2-dihydroxy-oct-yloxy pillar[5]arene 1,2-di-chloro-ethane monosolvate.

作者信息

Al-Azemi Talal F, Vinodh Mickey, Mohamod Abdirahman A, Alipour Fatemeh H

机构信息

Department of Chemistry, Kuwait University, PO Box 5969, Safat 13060, Kuwait.

出版信息

Acta Crystallogr E Crystallogr Commun. 2018 Sep 25;74(Pt 10):1471-1474. doi: 10.1107/S2056989018013415. eCollection 2018 Oct 1.

DOI:10.1107/S2056989018013415
PMID:30319804
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6176442/
Abstract

Crystals of 1-(1,4-dihy-droxy)-2,3,4,5-(1,4-dioct-yloxy)-pillar[5]arene, CHO·CHCl, were grown from a 1,2-dicholoro-ethane/-hexane solvent system. In the crystal, the encapsulated 1,2-di-chloro-ethane solvent is stabilized by C-H⋯π inter-actions and mediates the formation of an inter-locked supra-molecular polymer C-H⋯Cl inter-actions.

摘要

1-(1,4-二羟基)-2,3,4,5-(1,4-二辛氧基)-柱[5]芳烃·二氯乙烷（CHO·CHCl）晶体是从1,2-二氯乙烷/正己烷溶剂体系中生长出来的。在晶体中，被包封的1,2-二氯乙烷溶剂通过C-H⋯π相互作用得以稳定，并介导形成一种由C-H⋯Cl相互作用构成的互锁超分子聚合物。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a869/6176442/da4a584692c8/e-74-01471-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a869/6176442/a94ce11e5e18/e-74-01471-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a869/6176442/0bf34ac2b3ac/e-74-01471-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a869/6176442/da4a584692c8/e-74-01471-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a869/6176442/a94ce11e5e18/e-74-01471-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a869/6176442/0bf34ac2b3ac/e-74-01471-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a869/6176442/da4a584692c8/e-74-01471-fig3.jpg

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