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ZnO/骨炭复合材料的合成及其光催化性能

Synthesis and Photocatalytic Performance of ZnO/Bone Char Composite.

作者信息

Jia Puqi, Tan Hongwei, Liu Kuiren, Gao Wei

机构信息

College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, China.

Department of Nonferrous Metallurgy, School of Metallurgy, Northeastern University, Shenyang 110819, China.

出版信息

Materials (Basel). 2018 Oct 15;11(10):1981. doi: 10.3390/ma11101981.

Abstract

ZnO/bone char (ZnO/BC) composites were successfully synthesized by the precipitation of a ZnO precursor on pyrolytic bone char. The effects of bone char size, mass ratio of ZnO to BC, and molar ratio of ZnO to triethylamine (TEA) on the microstructure, specific surface area, and light absorbance of ZnO/BC were studied. The photocatalytic property of ZnO/BC was evaluated by the degradation of methylene blue. Results show that with a uniform nano-ZnO particle layer distributed evenly on the bone char surface, ZnO/BC has the strongest light absorbance and can effectively degrade methylene blue. The photocatalytic performance of ZnO/BC is related to the light absorbance of the photocatalyst, as well as the amount and distribution state of the loaded ZnO. This study indicates that bovine bone waste can be used as a nano-photocatalyst carrier to prepare photocatalytic composites, which is not only a good way to clean wastewater but also an ideal solution to utilize animal bone waste.

摘要

通过在热解骨炭上沉淀氧化锌前驱体成功合成了氧化锌/骨炭(ZnO/BC)复合材料。研究了骨炭尺寸、ZnO与BC的质量比以及ZnO与三乙胺(TEA)的摩尔比对ZnO/BC微观结构、比表面积和光吸收率的影响。通过亚甲基蓝的降解来评估ZnO/BC的光催化性能。结果表明,ZnO/BC在骨炭表面均匀分布着一层均匀的纳米ZnO颗粒层,具有最强的光吸收率,能有效降解亚甲基蓝。ZnO/BC的光催化性能与光催化剂的光吸收率以及负载ZnO的量和分布状态有关。本研究表明,牛骨废弃物可作为纳米光催化剂载体来制备光催化复合材料,这不仅是一种处理废水的好方法,也是利用动物骨废弃物的理想解决方案。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/303f/6213724/4d659361face/materials-11-01981-g001.jpg

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