Novel starch-mediated synthesis of Au/ZnO nanocrystals and their photocatalytic properties.

A novel solution-solid synthesis method for preparation of ZnO and Au/ZnO composite nanocrystals using starch matrix has been developed and optimized. The process is characterized by simplicity, environmental compatibility and good performance. Nanocomposite samples with different gold content have been synthesized and studied with respect to their structure, size and shape of nanocrystals, thermal behavior, surface characteristics and optical properties, as well as their photocatalytic activity. We have found that modification of nanocrystalline ZnO with gold nanocrystals strongly influences the porosity of nanocomposites - less micro- and mesopores are formed, which results in a reduced specific surface area. The synthesized ZnO and Au/ZnO nanocrystals are active photocatalysts for the photocatalytic degradation of methylene blue (MB), as a model pollutant dye, in the UV region. There is a decrease in photocatalytic activity with an increase of the gold content in the nanocomposite photocatalyst. The degree of MB degradation obtained with a pure ZnO sample is comparable to that with the Au/ZnO photocatalyst with the lowest gold content 0.05 at. %. New and interesting result has been obtained relating to maximum specific (intrinsic) photocatalytic activity of 0.05 at. % Au/ZnO nanocrystals.