Department of Chemistry, WACKER-Institute of Silicon Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstraße 4, 85748 Garching bei München, Germany.
Chem Commun (Camb). 2018 Dec 4;54(97):13658-13661. doi: 10.1039/c8cc07754a.
The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me2S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.
首次报道了硅亚基鎓离子的金属配合物。用过渡金属前体（CuCl、AgOTf、(Me2S)AuCl）处理 N-杂环卡宾（NHC）稳定的硅亚基鎓离子（R = m-Ter、Tipp），得到了第一个硅亚基金属（M = Cu、Ag、Au）配合物，它们已经通过包括 X 射线衍射分析在内的方法进行了充分的表征。
