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观点:受限液体的动力学。

Perspective: Dynamics of confined liquids.

机构信息

Department of Chemistry, University of Kansas, Lawrence, Kansas 66045, USA.

出版信息

J Chem Phys. 2018 Nov 7;149(17):170901. doi: 10.1063/1.5057759.

Abstract

Liquids confined on nanometer lengthscales are ubiquitous in chemistry, occurring in systems ranging from mesoporous catalysts to the crowded interior of a cell. Understanding how the properties of the liquid in these environments differs from that in the corresponding bulk is key to interpreting measurements, developing methods for theoretical predictions, and controlling chemical pathways. This area has received significant attention in recent years, resulting in notable progress. In this perspective, we discuss the advances in understanding the dynamics of confined liquids as well as the nontrivial remaining challenges.

摘要

受限在纳米尺度范围内的液体在化学中无处不在,存在于从介孔催化剂到细胞拥挤内部的各种体系中。了解这些环境中液体的性质与相应体相中的液体性质有何不同,是解释测量结果、开发理论预测方法和控制化学途径的关键。近年来,该领域受到了广泛关注,取得了显著进展。在本观点中,我们讨论了在理解受限液体动力学方面的进展以及仍然存在的一些重要挑战。

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