Ghosh Arun K, Cho Hanna, Cappiello John
Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607, USA.
Tetrahedron Asymmetry. 1998 Oct 23;9(20):3687-3691. doi: 10.1016/S0957-4166(98)00362-0. Epub 2000 Jun 15.
Cationic aqua complex derived from bidentate inda-box ligand and Cu(ClO)·6HO is an excellent catalyst (5-10 mol%) for enantioselective (92-99% ) Diels-Alder reactions of cyclopentadiene and various bidentate dienophiles.
源自双齿茚盒配体和Cu(ClO)·6H₂O的阳离子水合配合物是一种出色的催化剂(5 - 10 mol%),用于环戊二烯与各种双齿亲双烯体的对映选择性(92 - 99%)狄尔斯-阿尔德反应。