Fibre and Particle Engineering Research Unit, Faculty of Technology, University of Oulu, P.O. Box 4300, 90014 Oulu, Finland.
Fibre and Particle Engineering Research Unit, Faculty of Technology, University of Oulu, P.O. Box 4300, 90014 Oulu, Finland.
Waste Manag. 2018 Oct;80:319-326. doi: 10.1016/j.wasman.2018.09.033. Epub 2018 Sep 22.
When aiming for higher resource efficiency, greater utilization of waste streams is needed. In this work, waste paper separated from mixed municipal solid waste (MSW) was studied as a potential starting material for the production of cellulose nanofibres (CNFs). The waste paper was treated using three different techniques, namely pulping, flotation and washing, after which it was subjected to an ultrafine grinding process to produce CNFs. The energy consumption of the nanofibrillation and nanofibre morphology, as well as properties of the prepared nanofibers, were analysed. Despite the varying amounts of impurities in the waste fibres, all samples could be fibrillated into nanoscale fibres. The tensile strengths of the CNF networks ranged from 70 to 100 MPa, while the stiffness was ∼7 GPa; thus, their mechanical strength can be adequate for applications in which high purity is not required. The contact angles of the CNF networks varied depending on the used treatment method: the flotation-treated networks were more hydrophilic (contact angle 52.5°) and the washed networks were more hydrophobic (contact angle 72.6°).
当目标是提高资源效率时,需要更大程度地利用废物流。在这项工作中,将从混合城市固体废物 (MSW) 中分离出的废纸作为生产纤维素纳米纤维 (CNF) 的潜在起始材料进行了研究。废纸经过制浆、浮选和洗涤三种不同的处理方法,然后进行超细研磨工艺以生产 CNF。分析了纳米纤维化的能量消耗和纳米纤维形态,以及制备的纳米纤维的性能。尽管废纤维中杂质的含量不同,但所有样品都可以被纤维化形成纳米级纤维。CNF 网络的拉伸强度范围为 70 至 100 MPa,而刚度约为 7 GPa;因此,它们的机械强度可以满足不需要高纯度的应用要求。CNF 网络的接触角取决于所用的处理方法:浮选处理的网络具有更好的亲水性(接触角为 52.5°),而洗涤的网络具有更好的疏水性(接触角为 72.6°)。
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