Department of Chemistry & Biochemistry, Baylor University, Waco, TX 76798, United States of America.
Department of Chemistry & Biochemistry, Baylor University, Waco, TX 76798, United States of America.
Spectrochim Acta A Mol Biomol Spectrosc. 2019 Mar 5;210:245-250. doi: 10.1016/j.saa.2018.11.034. Epub 2018 Nov 13.
In this paper, we describe in detail an assembled open-path optical cavity to act as a temperature sensor of air. A metal absorption cell in a temperature-regulated tube furnace is placed at the center of an optical cavity. The optical cavity consists of two mirrors, two nitrogen buffer sleeves, and the open cell. The air is injected through a fitting in one extreme of the metal tube and travels half the tube length through a channel in the wall of the tube. The channel directs the air towards the center of the cell. The air flowing is heated at the temperature of the metal tube in contact with the furnace. The heated air injected at the center of the tube, flows towards the open extremes of the tube. The nitrogen buffer sleeves protect the mirrors from the heated air. The temperature of the air flowing through the tube is determined by measuring the absorption of the A band of oxygen as a function of the wavenumber in the 769-755 nm wavelength range. The absorption technique is phase-shift cavity ring down spectroscopy. To obtain the temperature, the energy of the lower rotational state for eleven selected rotational transitions is linearly fitted to a logarithmic function that contains the relative intensity of the rotational transition, the initial and final rotational quantum numbers and the energy of the transition. Accuracy of the measurement is determined by comparing the calculated temperature from the spectra with the analog reading of the temperature-regulated tube furnace. This technique is proposed for exhaust air temperature measurements of combustion chambers and cooling air after passing through the blades of a turbine.
本文详细描述了一种组装的开放式光腔,用作空气的温度传感器。一个置于温度可调管式炉内的金属吸收池位于光学腔的中心。光学腔由两个反射镜、两个氮气缓冲套管和开放式单元组成。空气通过金属管一端的配件注入,通过管壁上的通道在管内长度的一半处流动。该通道将空气引导至单元的中心。与炉子接触的金属管的温度会加热流动的空气。注入管中心的加热空气流向管的开口端。氮气缓冲套管保护镜子免受热空气的影响。通过测量氧 A 带在 769-755nm 波长范围内随波数的吸收来确定流过管的空气的温度。吸收技术是相移腔衰荡光谱学。为了获得温度,将十一个选定的转动跃迁的较低转动态的能量线性拟合到一个包含转动跃迁的相对强度、初始和最终转动量子数以及跃迁能量的对数函数中。通过将从光谱计算出的温度与温度可调管式炉的模拟读数进行比较来确定测量的准确性。该技术被提议用于测量燃烧室的废气温度和涡轮叶片后的冷却空气温度。