Enikolopov Institute of Synthetic Polymer Materials RAS, 70 Profsoyuznaya str., 117393, Moscow, Russia.
Soft Matter. 2018 Dec 12;14(48):9755-9759. doi: 10.1039/c8sm02145g.
Variation of generation number strongly affects the type of ordering found for polybutylcarbosilane dendrimers: G5 dendrimers are liquid-like, G6 are cubic liquid crystals and G7/G8 are disordered close-packed. It was revealed that G6 dendrimers are highly likely to form Im3[combining macron]m lattice structures with the parameter a = 5.15 nm, and a domain size that exceeds 100 nm.
G5 树枝状分子为液态，G6 树枝状分子为立方液晶，G7/G8 树枝状分子为无序密堆积。研究表明，G6 树枝状分子极有可能形成 Im3[combining macron]m 晶格结构，参数 a = 5.15nm，畴尺寸超过 100nm。
