Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000 Zagreb, Croatia.
Man-Environment-Technology Research Centre, School of Science and Technology, Örebro University, Gymnastikgatan 1, 70182 Örebro, Sweden.
Int J Environ Res Public Health. 2018 Nov 27;15(12):2674. doi: 10.3390/ijerph15122674.
Walnuts () are considered to be a functional food. In the present study, twenty one macro-, micro-, and trace elements (Al, As, B, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Se, Sr, and Zn) were selected to be determined in walnuts and walnut oils. The beneficial content of essential elements could be shown by the obtained results, the macro-elements Ca, K, Mg, and Na being present in nuts with 1062 mg/kg, 2771 mg/kg, 1426 mg/kg, and 42.3 mg/kg, respectively. Regarding micro- and trace elements, the following order (decreasing content) was found: Mn > Fe > Zn > B, Mo > Cu > Ni > Co > Al > Sr > Ba > Li > Pb > Se > Cr > As > Cd. Furthermore, the potentially toxic trace elements (As, Cd, Pb) determined were below the maximum allowed values in most of the investigated walnut samples. A comparison of oils and nuts revealed that the former contain lower concentrations of all elements analyzed except for Fe and Zn. This suggested the origin from contamination during oil processing. Fe influences the oil oxidation rate, thus its entry during production should be avoided.
核桃()被认为是一种功能性食品。在本研究中,选择了二十一种宏量、微量和痕量元素(Al、As、B、Ba、Ca、Cd、Co、Cr、Cu、Fe、K、Li、Mg、Mn、Mo、Na、Ni、Pb、Se、Sr 和 Zn)来测定核桃和核桃油中的含量。通过获得的结果可以看出有益的必需元素含量,坚果中存在的宏量元素 Ca、K、Mg 和 Na 分别为 1062mg/kg、2771mg/kg、1426mg/kg 和 42.3mg/kg。至于微量元素和痕量元素,其含量顺序(递减)为:Mn>Fe>Zn>B,Mo>Cu>Ni>Co>Al> Sr>Ba>Li>Pb>Se>Cr>As>Cd。此外,在所研究的大多数核桃样本中,测定的潜在有毒痕量元素(As、Cd、Pb)均低于允许的最大值。油和坚果的比较表明,除了 Fe 和 Zn 之外,前者含有所有分析元素的浓度较低。这表明在油加工过程中存在污染。Fe 影响油的氧化速率,因此在生产过程中应避免其进入。