CAS Key Laboratory of Design a Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China.
Group for Molecular Engineering of Functional Materials, Institute of Chemical Sciences and Engineering, École Polytechnique Fedérale de Lausanne, 1951, Sion, Switzerland.
Nat Commun. 2018 Nov 28;9(1):5028. doi: 10.1038/s41467-018-07382-9.
Hybrid halide perovskite solar cells were first demonstrated in 2009 with cell efficiency quickly soaring from below 10% to more than 23% in a few years. Halide perovskites have the desirable processing simplicity but are very fragile when exposed to water and heat. This fragility represents a great challenge for the achievement of their full practical potential in photovoltaic technologies. To address this problem, here we review the recent development of the mixed-dimensional perovskites, whereby the trade-off between power conversion efficiency and stability of the material can be finely tuned using organic amine cations with different sizes and functionalities.
混合卤化物钙钛矿太阳能电池于 2009 年首次被证明，其电池效率在短短几年内迅速从低于 10%飙升至超过 23%。卤化物钙钛矿具有理想的加工简单性，但暴露在水和热中时非常脆弱。这种脆弱性对实现其在光伏技术中的全部实际潜力构成了巨大挑战。为了解决这个问题，我们在这里回顾了混合维钙钛矿的最新发展，通过使用具有不同大小和功能的有机胺阳离子，可以精细地调整材料的功率转换效率和稳定性之间的权衡。
