[BHNH₃]氨基十二硼烷阴离子的脒、酰胺、脲和异氰酸酯衍生物的合成与结构表征
Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino--dodecaborate Anion [BHNH₃].
机构信息
Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China.
Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China.
出版信息
Molecules. 2018 Nov 29;23(12):3137. doi: 10.3390/molecules23123137.
The synthesis and structural characterization of new derivatives of [BH] is of fundamental interest and is expected to allow for extended applications. Herein we report on the synthesis of a series of amidine, amide, urea and isocyanate derivatives based on the amino--dodecaborate anion [BHNH₃]. Their structures have been confirmed by spectroscopic methods, and nine crystal structures are presented.
新型[BH]衍生物的合成和结构表征具有重要意义，有望扩展其应用。在此，我们报告了一系列基于氨基-十二硼酸盐阴离子[BHNH₃]的脒、酰胺、脲和异氰酸酯衍生物的合成。它们的结构通过光谱方法得到了确认，并呈现了九个晶体结构。
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