作为多响应性十二硼酸盐-葫芦脲超分子网络的正交组装基序的离液序列高聚物效应
The chaotropic effect as an orthogonal assembly motif for multi-responsive dodecaborate-cucurbituril supramolecular networks.
作者信息
Wang Wenjing, Wang Xiaoqiang, Cao Jin, Liu Jun, Qi Bin, Zhou Xiaohai, Zhang Shuai, Gabel Detlef, Nau Werner M, Assaf Khaleel I, Zhang Haibo
机构信息
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China.
Hubei Gedian Humanwell Pharmaceutical Excipents Co., Ltd, Gedian 436070, China.
出版信息
Chem Commun (Camb). 2018 Feb 22;54(17):2098-2101. doi: 10.1039/c7cc08078f.
In aqueous solution, host-guest complexation is frequently driven by the hydrophobic effect, which also constitutes a popular approach in the design of supramolecular assemblies. Herein, we report an orthogonal assembly motif, the chaotropic effect, which exploits the tendency of chaotropic anions to associate with hydrophobic surfaces.
在水溶液中，主客体络合作用通常由疏水效应驱动，疏水效应也是超分子组装体设计中一种常用的方法。在此，我们报道了一种正交组装基序——离液序列高的阴离子效应，该效应利用了离液序列高的阴离子与疏水表面结合的倾向。
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