Department of Chemistry, Urumu Dhanalakshmi College, Tiruchirappalli 620019, Tamil Nadu, India.
Department of Agricultural Microbiology, Horticultural College and Research Institute for Women, Navalur Kuttappattu, Tiruchirappalli 620009, Tamil Nadu, India.
J Nanosci Nanotechnol. 2019 May 1;19(5):2888-2894. doi: 10.1166/jnn.2019.16023.
Semiconductor ZnO samples with two different morphologies such as nanoparticles (ZnO-NPs) and nano-sheets (ZnO-NSs) was successfully prepared by microwave heating (MHM) and modified sol-gel (SGM) method, respectively using plant extract as the bio-reducing agent. Structural, purity and morphology of the samples was examined by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis. Optical property analysis and band gap calculation were carried out by UV-Visible diffuse reflectance (DRS) and photoluminescence (PL) spectroscopy techniques. Kubelka-Munk method was used to measure band band gap of the samples and it shows 3.42 eV and 3.23 eV for ZnO-NPs and ZnO-NSs, respectively. The antibacterial activities of ZnO-NPs and ZnO-NSs against both gram positive (, ) as well as gram negative bacteria (, ) were tested by modified disc diffusion method and showed important antibacterial activity against and The photocatalytic activity of ZnO nano-catalysts (ZnO-NPs and ZnO-NSs) for the degradation of methylene blue (MB) dye was studied under solar lighting and the results showed that the samples ZnO-NPs with smaller particle size considerable degradation of MB than ZnO-NSs.
采用微波加热 (MHM) 和改进的溶胶-凝胶 (SGM) 法,分别使用植物提取物作为生物还原剂,成功制备了具有两种不同形貌的半导体 ZnO 样品,即纳米粒子 (ZnO-NPs) 和纳米片 (ZnO-NSs)。通过 X 射线粉末衍射 (XRD)、扫描电子显微镜 (SEM) 结合能谱分析 (EDX) 对样品的结构、纯度和形貌进行了检测。通过紫外-可见漫反射 (DRS) 和光致发光 (PL) 光谱技术进行了光学性质分析和带隙计算。Kubelka-Munk 法用于测量样品的能带隙,结果表明 ZnO-NPs 和 ZnO-NSs 的能带隙分别为 3.42 eV 和 3.23 eV。采用改良的圆盘扩散法测试了 ZnO-NPs 和 ZnO-NSs 对革兰氏阳性菌 ( 和 ) 以及革兰氏阴性菌 ( 和 ) 的抗菌活性,结果表明它们对 和 具有重要的抗菌活性。在阳光照射下研究了 ZnO 纳米催化剂 (ZnO-NPs 和 ZnO-NSs) 对亚甲基蓝 (MB) 染料的光催化降解活性,结果表明粒径较小的 ZnO-NPs 比 ZnO-NSs 对 MB 有更好的降解效果。