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氧化锌纳米粒子的增强抗菌活性和光催化性能:植物提取物辅助合成。

Enhanced Antibacterial Activity and Photo-Catalytic Properties of ZnO Nanoparticles: Plant Extract-Assisted Synthesis.

机构信息

Department of Chemistry, Urumu Dhanalakshmi College, Tiruchirappalli 620019, Tamil Nadu, India.

Department of Agricultural Microbiology, Horticultural College and Research Institute for Women, Navalur Kuttappattu, Tiruchirappalli 620009, Tamil Nadu, India.

出版信息

J Nanosci Nanotechnol. 2019 May 1;19(5):2888-2894. doi: 10.1166/jnn.2019.16023.

Abstract

Semiconductor ZnO samples with two different morphologies such as nanoparticles (ZnO-NPs) and nano-sheets (ZnO-NSs) was successfully prepared by microwave heating (MHM) and modified sol-gel (SGM) method, respectively using plant extract as the bio-reducing agent. Structural, purity and morphology of the samples was examined by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis. Optical property analysis and band gap calculation were carried out by UV-Visible diffuse reflectance (DRS) and photoluminescence (PL) spectroscopy techniques. Kubelka-Munk method was used to measure band band gap of the samples and it shows 3.42 eV and 3.23 eV for ZnO-NPs and ZnO-NSs, respectively. The antibacterial activities of ZnO-NPs and ZnO-NSs against both gram positive (, ) as well as gram negative bacteria (, ) were tested by modified disc diffusion method and showed important antibacterial activity against and The photocatalytic activity of ZnO nano-catalysts (ZnO-NPs and ZnO-NSs) for the degradation of methylene blue (MB) dye was studied under solar lighting and the results showed that the samples ZnO-NPs with smaller particle size considerable degradation of MB than ZnO-NSs.

摘要

采用微波加热 (MHM) 和改进的溶胶-凝胶 (SGM) 法,分别使用植物提取物作为生物还原剂,成功制备了具有两种不同形貌的半导体 ZnO 样品,即纳米粒子 (ZnO-NPs) 和纳米片 (ZnO-NSs)。通过 X 射线粉末衍射 (XRD)、扫描电子显微镜 (SEM) 结合能谱分析 (EDX) 对样品的结构、纯度和形貌进行了检测。通过紫外-可见漫反射 (DRS) 和光致发光 (PL) 光谱技术进行了光学性质分析和带隙计算。Kubelka-Munk 法用于测量样品的能带隙,结果表明 ZnO-NPs 和 ZnO-NSs 的能带隙分别为 3.42 eV 和 3.23 eV。采用改良的圆盘扩散法测试了 ZnO-NPs 和 ZnO-NSs 对革兰氏阳性菌 ( 和 ) 以及革兰氏阴性菌 ( 和 ) 的抗菌活性,结果表明它们对 和 具有重要的抗菌活性。在阳光照射下研究了 ZnO 纳米催化剂 (ZnO-NPs 和 ZnO-NSs) 对亚甲基蓝 (MB) 染料的光催化降解活性,结果表明粒径较小的 ZnO-NPs 比 ZnO-NSs 对 MB 有更好的降解效果。

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