Multifunctional Self-Healing Ionogels from Supramolecular Assembly: Smart Conductive and Remarkable Lubricating Materials.

Self-healing ionogel is a promising smart material because of its high conductivity and reliable stimuli responsiveness upon mechanical damage. However, self-healing ionogels possessing rapid, complete recovery properties and multifunctionality are still limited. Herein, we designed a new d-gluconic acetal-based gelator (PB8) bearing a urea group in the alkyl side chain. Interestingly, the balance between hydrophilicity and hydrophobicity of the molecule is achieved. Thus, PB8 could form transparent ionogels because of its excellent affinity to ionic liquids (ILs), which exhibited appropriate mechanical strength, high viscoelasticity, and efficient self-healing properties. The presence of synergistic effects from hydrogen bonding, π-π stacking, and interactions between the urea-containing side chains was responsible for the self-assembly of gelators in ILs and the self-healing property mainly related to the side chains of PB8. Interestingly, the transparent PB8-IL4 ionogel possessed high conductivity and mechanical strength, moldable and injectable properties, and rapid and complete self-healing characteristics (complete recovery within 14 min), which showed excellent performance as a smart ionic conductor. Furthermore, the self-healing PB8-based ionogels with anticorrosion properties are a remarkable lubricating material in the steel-steel contact and exhibited excellent lubricating performances. Overall, an efficient PB8-based ionogel with self-healing properties has been developed for potential use both as a smart electrical conductor and as a high-performance lubricating material. The unique structure of PB8 bearing a urea group in the side chain is found to be responsible for the multifunctional ionogel formation.